ASYMMETRIC-SYNTHESIS CATALYZED BY CHIRAL FERROCENYLPHOSPHINE-TRANSITION METAL-COMPLEXES .9. PREPARATION OF CHIRAL FERROCENYLBISPHOSPHINES CONTAINING AN AMINOALKYL SIDE-CHAIN

被引：34

作者：

HAYASHI, T ^{[1
]}

YAMAZAKI, A ^{[1
]}

机构：

[1] HOKKAIDO UNIV,GRAD SCH PHARMACEUT SCI,SAPPORO,HOKKAIDO 060,JAPAN

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 413卷 / 1-3期

关键词：

D O I：

10.1016/0022-328X(91)80058-R

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New optically active ferrocenylbisphosphines containing an aminoalkyl pendant side chain were prepared. They are (R)-N-methyl-N-(2-piperidino)ethyl-1-[(S)-1',2-bis(diarylphosphino)ferrocenyl]ethylamines, where aryl groups on the phosphorus atoms are 4-CF3C6H4, 3-CF3C6H4, 4-FC6H4, 4-MeOC6H4, and 3,5-Me2-4-MeOC6H2.

引用

页码：295 / 302

页数：8

共 24 条

[1]

BRUNNER H, 1988, TOP STEREOCHEM, V18, P129

[2]

ELSLAGER EF, 1961, J ORG CHEM, V21, P2837

[3]

GOKEL GW, 1972, J ORG CHEM, V37, P3052, DOI 10.1021/jo00985a002

[4] ASYMMETRIC-SYNTHESIS CATALYZED BY CHIRAL FERROCENYLPHOSPHINE METAL-COMPLEXES [J].

HAYASHI, T .

PURE AND APPLIED CHEMISTRY, 1988, 60 (01) :7-12

[5] ASYMMETRIC HYDROGENATION OF TRISUBSTITUTED ACRYLIC ACIDS CATALYZED BY A CHIRAL (AMINOALKYL)FERROCENYLPHOSPHINE RHODIUM COMPLEX [J].

HAYASHI, T ;

KAWAMURA, N ;

ITO, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (25) :7876-7878

[6] ASYMMETRIC-SYNTHESIS CATALYZED BY CHIRAL FERROCENYLPHOSPHINE TRANSITION-METAL COMPLEXES .8. PALLADIUM-CATALYZED ASYMMETRIC ALLYLIC AMINATION [J].

HAYASHI, T ;

YAMAMOTO, A ;

ITO, Y ;

NISHIOKA, E ;

MIURA, H ;

YANAGI, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (16) :6301-6311

[7] ASYMMETRIC-SYNTHESIS CATALYZED BY TRANSITION-METAL COMPLEXES WITH FUNCTIONALIZED CHIRAL FERROCENYLPHOSPHINE LIGANDS [J].

HAYASHI, T ;

KUMADA, M .

ACCOUNTS OF CHEMICAL RESEARCH, 1982, 15 (12) :395-401

[8]

HAYASHI T, 1985, TETRAHEDRON LETT, V26, P3023, DOI 10.1016/S0040-4039(00)98608-8

[9] CATALYTIC ASYMMETRIC HYDROSILYLATION OF 1,3-DIENES WITH NEW CHIRAL FERROCENYLPHOSPHINE-PALLADIUM COMPLEXES [J].

HAYASHI, T ;

MATSUMOTO, Y ;

MORIKAWA, I ;

ITO, Y .

TETRAHEDRON-ASYMMETRY, 1990, 1 (03) :151-154

[10] OPTICALLY-ACTIVE ALLYLSILANES .10. ASYMMETRIC-SYNTHESIS CATALYZED BY CHIRAL FERROCENYLPHOSPHINE TRANSITION-METAL COMPLEXES .3. PREPARATION OF OPTICALLY-ACTIVE ALLYLSILANES BY PALLADIUM-CATALYZED ASYMMETRIC GRIGNARD CROSS-COUPLING [J].

HAYASHI, T ;

KONISHI, M ;

OKAMOTO, Y ;

KABETA, K ;

KUMADA, M .

JOURNAL OF ORGANIC CHEMISTRY, 1986, 51 (20) :3772-3781

← 1 2 3 →