STUDIES ON THE STRUCTURE OF ALPHA-BRANCHED-BETA-HYDROXYLATED FATTY-ACIDS FROM CORYNEBACTERIUM-OVIS (C-PSEUDOTUBERCULOSIS)

被引:11
作者
IONEDA, T [1 ]
SILVA, CL [1 ]
THOMAS, DW [1 ]
机构
[1] SRI INT, MENLO PK, CA 94025 USA
基金
巴西圣保罗研究基金会;
关键词
D O I
10.1016/0009-3084(79)90090-2
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
The composition of the α-branched-β-hydroxylated fatty acids from Corynebacterium ovis was studied. These acids were fractionated by argentation thin-layer chromatography in three species according to the degree of unsaturation of their O-acetylated methyl ester derivatives; the isolated fractions were analysed by gas chromatography combined with mass spectrometry. Corynomycolic (2-tetradecyl-3-hydroxy octadecanoic), corynomycolenic (2-tetradecyl-3-hydroxy-11-octadecenoic) and corynomycoldienic (2-tetradec-7′-enyl-3-hydroxy-11-octadecenoic) acids were identified; these acids represented the main component of the saturated, mono- and di-unsaturated species, respectively. On the other hand, a short-chain corynomycolic acid (2-tetradecyl-3-hydroxy decanoic acid), C24H48O3 was found. © 1979.
引用
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页码:1 / 9
页数:9
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