SIZE DEPENDENCE OF HF VIBRATIONAL FREQUENCY-SHIFT FOR ARNHF (N=1-14) VAN-DER-WAALS CLUSTERS VIA QUANTUM 5-DIMENSIONAL BOUND-STATE CALCULATIONS

被引：50

作者：

LIU, SY

BACIC, Z

MOSKOWITZ, JW

SCHMIDT, KE

机构：

[1] NYU,DEPT CHEM,NEW YORK,NY 10003

[2] ARIZONA STATE UNIV,DEPT PHYS & ASTRON,TEMPE,AZ 85287

来源：

JOURNAL OF CHEMICAL PHYSICS | 1994年 / 101卷 / 11期

关键词：

D O I：

10.1063/1.468007

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

HF vibrational frequency shifts for ArnHF (n=1-14) clusters have been determined for the first time using quantum 5D bound state calculations. Our results for n=1-4 clusters are in very good agreement with the available experimental data. The size dependence of the redshift is predicted to be very nonmonotonic. © 1994 American Institute of Physics.

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页码：10181 / 10184

页数：4

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