SOLVATION OF LITHIUM IONS IN MIXTURES OF TETRAETHYLENE GLYCOL DIMETHYL ETHER AND PROPYLENE CARBONATE

被引：26

作者：

FISH, D ^{[1
]}

SMID, J ^{[1
]}

机构：

[1] SUNY SYRACUSE,COLL ENVIRONM SCI & FORESTRY,FAC CHEM,POLYMER RES INST,SYRACUSE,NY 13210

来源：

ELECTROCHIMICA ACTA | 1992年 / 37卷 / 11期

关键词：

POLYMER ELECTROLYTES; SOLVATION; LITHIUM IONS; PROPYLENE CARBONATE; TETRAGLYME;

D O I：

10.1016/0013-4686(92)87120-O

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The effect of propylene carbonate (PC) on the solvation shell of lithium ions in solutions of lithium perchlorate and lithium picrate in tetraethylene glycol dimethyl ether (TEGDME) was studied as a function of PC content and temperature using C-13 NMR, conductance, and optical and infrared spectroscopy. The results show that while PC promotes the dissociation of the electrolyte into free ions, it is at the same time a relatively poor cation chelating agent, and most of the cations remain bound to TEGDME even up to 80 mass % (90 mol%) PC. The ramifications of these observations for PC-plasticized lithium-polymer electrolytes are discussed.

引用

页码：2043 / 2049

页数：7

共 42 条

[1]

ACCASCINA F, 1959, ELECTROLYTIC CONDUCT

[2]

Armand M., 1990, 2 INT S POL EL, P91

[3] POLYMER ELECTROLYTES [J].

ARMAND, MB .

ANNUAL REVIEW OF MATERIALS SCIENCE, 1986, 16 :245-261

[4] IONIC-CONDUCTIVITY IN ORGANIC-SOLIDS DERIVED FROM AMORPHOUS MACROMOLECULES [J].

BALLARD, DGH ;

CHESHIRE, P ;

MANN, TS ;

PRZEWORSKI, JE .

MACROMOLECULES, 1990, 23 (05) :1256-1264

[5]

BLONSKY PM, 1984, J AM CHEM SOC, V106, P6854, DOI 10.1021/ja00334a071

[6] INTERACTIONS OF MACROBICYCLIC POLYETHERS WITH IONS AND ION-PAIRS OF PICRATE SALTS [J].

BOURGOIN, M ;

WONG, KH ;

HUI, JY ;

SMID, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (12) :3462-3467

[7]

BRUNN VJ, 1977, Z PHYS CHEM, V258, P681

[8] CONDUCTIVITY AND VISCOSITY OF LIQUID POLYMER ELECTROLYTES PLASTICIZED BY PROPYLENE CARBONATE AND TETRAHYDROFURAN [J].

CAMERON, GG ;

INGRAM, MD ;

SARMOUK, K .

EUROPEAN POLYMER JOURNAL, 1990, 26 (10) :1097-1101

[9] COMPLEXATION OF LITHIUM, SODIUM, AND POTASSIUM CARBANION PAIRS WITH POLYGLYCOL DIMETHY ETHERS (GLYMES - EFFECT OF CHAIN LENGTH AND TEMPERATURE [J].

CHAN, LL ;

WONG, KH ;

SMID, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1970, 92 (07) :1955-+

[10] ASSOCIATION CONSTANTS OF POLYETHYLENEGLYCOL ETHERS WITH NA+, K+, CS+ AND TL+ [J].

CHAPUT, G ;

JEMINET, G ;

JUILLARD, J .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1975, 53 (15) :2240-2246

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