SIMULTANEOUS BINDING OF SOFT AND HARD METALS TO A PYRIMIDINE NUCLEOBASE - TRANS-K2[PTI2(1-MEU)2].6H2O, AN ANIONIC PT-1-METHYLURACIL (1-MEU) COMPLEX ARRANGED IN CIRCLES

被引：22

作者：

RENN, O

LIPPERT, B

MUTIKAINEN, I

机构：

[1] UNIV DORTMUND, FACHBEREICH CHEM, D-44221 DORTMUND, GERMANY

[2] UNIV HELSINKI, DEPT CHEM, SF-00100 HELSINKI 10, FINLAND

来源：

INORGANICA CHIMICA ACTA | 1994年 / 218卷 / 1-2期

关键词：

CRYSTAL STRUCTURES; PLATINUM COMPLEXES; URACIL COMPLEXES; NUCLEOBASE COMPLEXES; ANIONIC COMPLEXES;

D O I：

10.1016/0020-1693(93)03794-B

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The anionic complex trans-[PtI2(1-MeU-N3)2]2- (1-MeU=1-methyluracil anion, C5H5N2O2), as its K salt, forms a supramolecular assembly with anionic entities linked via K+ cations and bridging H2O molecules. The Pt coordination sphere is normal square-planar. Crystallographic data are as follows: C10H22I2K2N4O10Pt, rhombohedral, space group R3BAR, a=26.166(4), c=9.245(2) angstrom, U=5482(3) angstrom3, Z=9. The structure was refined to R=3.46, R(w)=4.63 for 1813 unique reflections with I>3sigma(I).

引用

页码：117 / 120

页数：4

共 19 条

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Istituto Chimico Farmaceutico, Università di Milano, I-20131 Milan, Italy
不详
Inorg. Chim. Acta, 2 (313-318):
[2] H3O2- bridging in a Pt(IV) nucleobase complex leading to infinite chains: trans,trans,trans-[Pt(NH3)(2)-(1-MeU)(2)(H3O2)](n)(NO3)(n)center dot(4H(2)O)(n) (1-MeU=1-methyluracilate)
Lianza, F
Albinati, A
Lippert, B
INORGANICA CHIMICA ACTA, 1997, 255 (02) : 313 - 318
[3] Detection and measurement of noncoincidence between the principal axes of the g-matrix and zero-field splitting tensor using multifrequency powder EPR spectroscopy:: Application to cis-[(NH3)2Pt(1-MeU)2Cu(H2O)2](SO4)•4.5H2O (1-MeU = monoanion of 1-methyluracil)
Collison, D
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INORGANIC CHEMISTRY, 2002, 41 (11) : 2826 - 2833
[4] THE MOLECULAR-STRUCTURES OF AU(2,2'-BPY)CL3.2.25H2O AND ITS 1-METHYLURACIL ADDUCT [AU(2,2'-BPY)(1-MEU)2]CLO4.4H2O
MICKLITZ, W
LIPPERT, B
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INORGANICA CHIMICA ACTA, 1989, 165 (01) : 57 - 64
[5] 1-METHYLURACIL (HMEU) AS A TETRADENTATE LIGAND - CRYSTAL-STRUCTURE OF TRANS(NH3)2PT(MEU)2AG2(NO3)2(H2O).H2O
SCHOLLHORN, H
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LIPPERT, B
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[6] SIMULTANEOUS BINDING OF SOFT AND HARD METALS TO A PYRIMIDINE NUCLEOBASE - PREPARATION AND X-RAY STRUCTURE OF [(EN)PD(1-MET)(2)NA-2](NO3)(2)CENTER-DOT-H2O (1-MET=1-METHYLTHYMINE ANION)
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INORGANICA CHIMICA ACTA, 1994, 227 (01) : 5 - 10
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TROTSCHER, G
MICKLITZ, W
SCHOLLHORN, H
THEWALT, U
LIPPERT, B
INORGANIC CHEMISTRY, 1990, 29 (13) : 2541 - 2547
[8] Ternary complex of cisplatin with glycine and 1-methyluracil: cis-[(NH3)(2)Pt(glyH-N)(1-MeU-N-3)]ClO4 center dot H2O
Hohmann, S
Erxleben, A
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Lippert, B
INORGANICA CHIMICA ACTA, 1996, 247 (01) : 79 - 83
[9] Growth Kinetics of the (110) Faces of Complex Potassium Cobalt-Nickel Sulphate K2CoxNi1-x(SO4)2•6H2O Crystals
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Grebenev, Vadim V.
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Manomenova, Vera L.
Kim, Ekaterina L.
Voloshin, Alexey E.
CRYSTALS, 2021, 11 (06): : NA
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PITTERI, B
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GILLI, G
FERRETTI, V
INORGANICA CHIMICA ACTA, 1991, 185 (02) : 201 - 210

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