MONODISPERSE POLYMER BEADS AS PACKING MATERIAL FOR HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY - SYNTHESIS AND PROPERTIES OF MONODISPERSE POLYSTYRENE AND POLY(METHACRYLATE) LATEX SEEDS

被引：0
作者：
SMIGOL, V
SVEC, F
HOSOYA, K
WANG, Q
FRECHET, JMJ
机构：
[1] CZECHOSLOVAK ACAD SCI,INST MACROMOLEC CHEM,CS-16206 PRAGUE 6,CZECHOSLOVAKIA
[2] CORNELL UNIV,DEPT CHEM,ITHACA,NY 14853
来源：
ANGEWANDTE MAKROMOLEKULARE CHEMIE | 1992年 / 195卷
关键词：
D O I：
暂无
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The effects of initiator concentration, ionic strength of polymerization medium, polymerization temperature, and monomer/water phase ratio on particle size, particle size distribution and molecular weight of the resulting polymers prepared by an emulsifier-free emulsion polymerization of styrene, methyl methacrylate and glycidyl methacrylate have been studied. Optimal conditions for preparation of uniformly sized polystyrene particles larger than 1-mu-m have been found. An attempt to synthesize monodisperse particles of similar size from methacrylate monomers and crosslinked particles has failed. It is shown that the swelling ability of "non-activated" latex particles does not exceed 70 fold increase in the volume and strongly depends on the size of the original particles.
引用
收藏
页码：151 / 164
页数：14
相关论文
共 22 条
  • [1] THE KINETICS OF POLYMERISATION REACTIONS IN AQUEOUS SOLUTION
    BAXENDALE, JH
    EVANS, MG
    KILHAM, JK
    [J]. TRANSACTIONS OF THE FARADAY SOCIETY, 1946, 42 (11): : 668 - 675
  • [2] BRADFORD EB, 1953, J APPL PHYS, V26, P864
  • [3] Chung-Li Y., 1976, PROG COLLOID POLYM S, V60, P163
  • [4] MONOSIZED STATIONARY PHASES FOR CHROMATOGRAPHY
    ELLINGSEN, T
    AUNE, O
    UGELSTAD, J
    HAGEN, S
    [J]. JOURNAL OF CHROMATOGRAPHY, 1990, 535 (1-2): : 147 - 161
  • [5] Fitch R. M., 1969, J POLYM SCI C, V27, P95
  • [6] GOODALL AR, 1977, J POLYM SCI POL CHEM, V15, P2193, DOI 10.1002/pol.1977.170150912
  • [7] CONTROL OF PARTICLE-SIZE IN FORMATION OF POLYMER LATTICES
    GOODWIN, JW
    OTTEWILL, RH
    PELTON, R
    VIANELLO, G
    YATES, DE
    [J]. BRITISH POLYMER JOURNAL, 1978, 10 (03): : 173 - 180
  • [8] STUDIES ON THE PREPARATION AND CHARACTERIZATION OF MONODISPERSE POLYSTYRENE LATTICES .5. PREPARATION OF CATIONIC LATTICES
    GOODWIN, JW
    OTTEWILL, RH
    PELTON, R
    [J]. COLLOID AND POLYMER SCIENCE, 1979, 257 (01) : 61 - 69
  • [9] Goodwin JW, 1973, BRIT POLYM J, V5, P347
  • [10] PREPARATION OF LARGE-PARTICLE-SIZE MONODISPERSE LATEXES IN A ROTATING-CYLINDER REACTOR
    KIM, JH
    SUDOL, ED
    ELAASSER, MS
    VANDERHOFF, JW
    KORNFELD, DM
    [J]. CHEMICAL ENGINEERING SCIENCE, 1988, 43 (08) : 2025 - 2030
123