ORGANOMETALLIC COMPOUNDS WITH METAL-METAL BONDS .15. SYNTHESIS AND INFRARED SPECTRA OF MONO(TETRACARBONYLCOBALT) DERIVATIVES OF TIN TETRAKIS(TETRACARBONYLCOBALT)TIN(4) AND RELATED COMPOUNDS

被引：86

作者：

PATMORE, DJ

GRAHAM, WAG

机构：

[1] Department of Chemistry, University of Alberta, Edmonton, Alberta

来源：

INORGANIC CHEMISTRY | 1968年 / 7卷 / 04期

关键词：

D O I：

10.1021/ic50062a031

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The syntheses and infrared spectra of a series of mono(tetracarbonylcobalt)tin(IV) derivatives of the general formula RnX3-x-SnCo(CO)4 [R = C6H5; X = Cl, Br, I; n = 0, 1, 2] are reported. Several triphenylphosphine complexes are also described. Assignments are suggested for the carbonyl stretching bands. Cobalt carbonyl reacts with tin(II) fluoride to form FSn-[Co(CO)4]3 and with tin(II) acetate to yield (CH3CO2)2Sn[Co(CO)4]2 and (CH3CO2)Sn[Co(CO)4]3. The preparation of Sn-[Co(CO)4]4 is also reported. © 1968, American Chemical Society. All rights reserved.

引用

页码：771 / +

共 16 条

[1]

BIGORGNE M, 1967, CR ACAD SCI C CHIM, V264, P2055

[2]

COATES GE, 1960, ORGANOMETALLIC COMPO, P183

[3] ASSIGNMENT OF CBONDO STRETCHING ABSORPTIONS IN C4NU METAL PENTACARBONYL DERIVATIVES - METHOD OF LOCAL OSCILLATING DIPOLES [J].