SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF (NEOPENTYL)(OCTAETHYLPORPHYRINATO)RUTHENIUM COMPLEXES, INCLUDING [RU(OEP)NP]2(MU-LI)2

被引：25

作者：

ALEXANDER, CS ^{[1
]}

RETTIG, SJ ^{[1
]}

JAMES, BR ^{[1
]}

机构：

[1] UNIV BRITISH COLUMBIA,DEPT CHEM,VANCOUVER V6T 1Z1,BC,CANADA

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 07期

关键词：

D O I：

10.1021/om00019a002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of neopentyllithium (LiNp) with the octaethylporphyrin complex Ru(OEP)Cl2 yields Ru-(OEP)Np (1), which can be treated with further LiNp to give [Ru(OEP)Np]2(mu-Li)2 (2). The structures of 1 (the first for an iron-group metalloporphyrin alkyl) and the more remarkable 2, revealing two Li atoms sandwiched between metalloporphyrin moieties, are determined.

引用

页码：2542 / 2544

页数：3