SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF (NEOPENTYL)(OCTAETHYLPORPHYRINATO)RUTHENIUM COMPLEXES, INCLUDING [RU(OEP)NP]2(MU-LI)2

被引：25

作者：

ALEXANDER, CS ^{[1
]}

RETTIG, SJ ^{[1
]}

JAMES, BR ^{[1
]}

机构：

[1] UNIV BRITISH COLUMBIA,DEPT CHEM,VANCOUVER V6T 1Z1,BC,CANADA

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 07期

关键词：

D O I：

10.1021/om00019a002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of neopentyllithium (LiNp) with the octaethylporphyrin complex Ru(OEP)Cl2 yields Ru-(OEP)Np (1), which can be treated with further LiNp to give [Ru(OEP)Np]2(mu-Li)2 (2). The structures of 1 (the first for an iron-group metalloporphyrin alkyl) and the more remarkable 2, revealing two Li atoms sandwiched between metalloporphyrin moieties, are determined.

引用

页码：2542 / 2544

页数：3

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[1] Synthesis and structural characterization of (neopentyl)(octaethylporphyrinato)ruthenium complexes, including [Ru(OEP)Np]2(μ-Li)2 [J].

Alexander, C.S. ;

Rettig, S.J. ;

James, B.R. .

Organometallics, 1994, 13 (07)

[2] Synthesis, characterization, and structure of (mu-sulfido)bis[(octaethylporphyrinato)ruthenium(III)], [Ru(OEP)](2)S [J].

Yee, GT ;

Noll, BC ;

Williams, DKC ;

Sellers, SP .

INORGANIC CHEMISTRY, 1997, 36 (13) :2904-&

[3] CHEMISTRY OF (OCTAETHYLPORPHYRINATO)LUTETIUM AND (OCTAETHYLPORPHYRINATO)YTTRIUM COMPLEXES - SYNTHESIS AND REACTIVITY OF (OEP)MX DERIVATIVES AND THE SELECTIVE ACTIVATION OF O2 BY (OEP)Y(MU-ME)2ALME2 [J].

SCHAVERIEN, CJ ;

ORPEN, AG .

INORGANIC CHEMISTRY, 1991, 30 (26) :4968-4978

[4] Synthesis and X-ray structural characterization of the ruthenium β-diketonato complexes:: Ru(hfac)3, cis-Ru(hfac)2(MeCN)2, and cis-Ru(hfac)(acac)(MeCN)2 [J].

Baird, IR ;

Rettig, SJ ;

James, BR ;

Skov, KA .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1999, 77 (11) :1821-1833

[5] Synthesis, characterization and DNA binding studies of ruthenium(II) complexes: [Ru(bpy)2(dtmi)]2+ and [Ru(bpy)2(dtni)]2+ [J].

Yun-Jun Liu ;

Xin Yu Wei ;

Wen-Jie Mei ;

Li-Xin He .

Transition Metal Chemistry, 2007, 32 :762-768

[6] Synthesis, characterization and DNA binding studies of ruthenium(II) complexes:: [Ru(bpy)2(dtmi)]2+ and [Ru(bpy)2(dtni)]2+ [J].

Liu, Yun-Jun ;

Wei, Xin Yu ;

Mei, Wen-Jie ;

He, Li-Xin .

TRANSITION METAL CHEMISTRY, 2007, 32 (06) :762-768

[7] THE USE OF RUTHENIUM TRIFLUOROMETHANESULFONATES IN THE SYNTHESIS OF [RU(CO)2(BIDENTATE)2]2+ COMPLEXES [J].

BLACK, DSC ;

DEACON, GB ;

THOMAS, NC .

TRANSITION METAL CHEMISTRY, 1980, 5 (05) :317-318

[8] Synthesis, characterization, and DNA-binding studies of ruthenium complexes [Ru(tpy)(ptn)]2+ and Ru(dmtpy)(ptn)]2+ [J].

Li, Lu-Ying ;

Jia, Hai-Na ;

Yu, Hui-Juan ;

Du, Ke-Jie ;

Lin, Qi-Tian ;

Qiu, Kang-Qiang ;

Chao, Hui ;

Ji, Liang-Nian .

JOURNAL OF INORGANIC BIOCHEMISTRY, 2012, 113 :31-39

[9] Synthesis and structural characterization of ruthenium complexes with 1-aryl-imidazole-2-thione [J].

Qin, Yi ;

Ma, Qing ;

Jia, Ai-Quan ;

Chen, Qun ;

Zhang, Qian-Feng .

JOURNAL OF COORDINATION CHEMISTRY, 2013, 66 (08) :1405-1415

[10] Synthesis and characterization of ruthenium(II) complexes of 2′-hydroxychalcones [J].

Silva, AMS ;

Cavaleiro, JAS ;

Tarrago, G ;

Marzin, C .

NEW JOURNAL OF CHEMISTRY, 1999, 23 (03) :329-335

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