SYNTHESIS AND SOLUTION PROPERTIES OF POLY[N,N'-(P-PHENYLENE)-3,3',4,4'-BIPHENYLTETRACARBOXYLIC ACID DIAMIDE]

被引：13
|
作者：
SWANSON, SA [1 ]
COTTS, PM [1 ]
SIEMENS, R [1 ]
KIM, SH [1 ]
机构：
[1] IBM CORP,ALMADEN RES CTR,DIV RES,650 HARRY RD,SAN JOSE,CA 95120
来源：
MACROMOLECULES | 1991年 / 24卷 / 06期
关键词：
D O I：
10.1021/ma00006a021
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The polyimide poly[N,N'-(p-phenylene)-3,3',4,4'-biphenyltetracarboxylic acid diimide] (BPDA-PDA) is used as a dielectric material in the electronics industry. Although the imidized polymer is insoluble in any organic solvent, the precursor polyamic acid is soluble in amide-type solvents or dimethyl sulfoxide (DMSO). A series of 10 polymers from the polycondensation of 3,3',4,4'-biphenyltetracarboxylic acid dianhydride (BPDA) and p-phenylenediamine (PDA) with 4800 < M(w) < 75 000 have been synthesized by controlling the stoichiometry. The solution properties were investigated in NMP (N-methylpyrrolidinone) and DMSO by using low-angle light scattering, viscometry, and size exclusion chromatography with a light scattering detector. Estimates of the molecular flexibility from the dilute solution properties are compared with those calculated based on a freely rotating model.
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页码：1352 / 1357
页数：6
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