FRAGMENTATION OF, AND OXYGEN-ATOM ABSTRACTION BY, (CP-ASTERISK-RE(O))(2)(MU-O)(2)

被引：28

作者：

GABLE, KP

JULIETTE, JJJ

GARTMAN, MA

机构：

[1] Department of Chemistry, Oregon State University, Corvallis

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 07期

关键词：

D O I：

10.1021/om00007a007

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The dimeric oxo complex (Cp*ReO)(2)(mu-O)(2) is found to be in equilibrium with a monomeric form, proposed to be Cp*ReO2. The mixture of monomer and dimer stereospecifically abstracts oxygen from epoxides to make alkene plus Cp*ReO3.

引用

页码：3138 / 3140

页数：3

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