DOUBLE GERMYLATION OF UNSATURATED CARBON-COMPOUNDS WITH DIGERMANES IN THE PRESENCE OF PALLADIUM AND PLATINUM CATALYSTS

被引：54

作者：

HAYASHI, T

YAMASHITA, H

SAKAKURA, T

UCHIMARU, Y

TANAKA, M

机构：

来源：

CHEMISTRY LETTERS | 1991年 / 02期

关键词：

D O I：

10.1246/cl.1991.245

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Double germylation of acetylenes, isoprene, and ethylene with 1,2-dichloro-1,1,2,2-tetramethyldigermane proceeds in the proceeds in the presence of palladium-and platinum-phosphorus ligand complexes to afford alpha, omega-bis(chlorodimethylgermyl) compounds in moderate to good yields.

引用

收藏

页码：245 / 248

页数：4

相关论文

共 10 条

[1] X-RAY-INDUCED REACTIONS AND RESIST FEATURES OF POLYDIBUTYLGERMANE [J].

BAN, H ;

DEGUCHI, K ;

TANAKA, A .

JOURNAL OF APPLIED POLYMER SCIENCE, 1989, 37 (06) :1589-1593

[2] TEMPERATURE-DEPENDENCE OF THE 3RD-ORDER NONLINEAR OPTICAL SUSCEPTIBILITIES IN POLYSILANES AND POLYGERMANES [J].

BAUMERT, JC ;

BJORKLUND, GC ;

JUNDT, DH ;

JURICH, MC ;

LOOSER, JH ;

MILLER, RD ;

RABOLT, J ;

SOORIYAKUMARAN, R ;

SWALEN, JD ;

TWIEG, RJ .

APPLIED PHYSICS LETTERS, 1988, 53 (13) :1147-1149

[3]

Corey J. Y., 1988, SILICON CHEM

[4]

COURET C, 1977, J ORGANOMET CHEM, V132, pC5

[5] PLATINUM COMPLEX-CATALYZED DEHYDROGENATIVE MONOSILYLATION OF ALKENES WITH DISILANES [J].

HAYASHI, T ;

KAWAMOTO, AM ;

KOBAYASHI, TA ;

TANAKA, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (07) :563-564

[6] PLATINUM-COMPLEX-CATALYZED DOUBLE SILYLATION OF ETHYLENE AND NORBORNENE WITH DISILANES [J].

HAYASHI, T ;

KOBAYASHI, T ;

KAWAMOTO, AM ;

YAMASHITA, H ;

TANAKA, M .

ORGANOMETALLICS, 1990, 9 (01) :280-281

[7] ADDITION OF CHLORODISILANES TO ACETYLENE CATALYZED BY TETRAKIS(TRIPHENYLPHOSPHINE)PALLADIUM(O) - A FACILE ROUTE TO (Z)-1,2-BIS(CHLOROSILYL)ETHENES [J].

MATSUMOTO, H ;

MATSUBARA, I ;

KATO, T ;

SHONO, K ;

WATANABE, H ;

NAGAI, Y .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1980, 199 (01) :43-47

[8] SOLUBLE ALKYL SUBSTITUTED POLYGERMANES - THERMOCHROMIC BEHAVIOR [J].

MILLER, RD ;

SOORIYAKUMARAN, R .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1987, 25 (01) :111-125

[9] A PALLADADIGERMETANE - PALLADIUM-CATALYZED INSERTION REACTIONS OF DIGERMIRANES [J].

TSUMURAYA, T ;

ANDO, W .

ORGANOMETALLICS, 1989, 8 (09) :2286-2288

[10]

Zeigler JM, 1990, ADV CHEM SER, V224