SYNTHESIS OF ALPHA-(HALOMETHYL)CYCLOALKANONES

被引：18
作者：
WENKERT, E
ARRHENIUS, TS
BOOKSER, B
GUO, M
MANCINI, P
机构：
[1] Department of Chemistry (D-006), University of California—San Diego, La Jolla
来源：
JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 04期
关键词：
D O I：
10.1021/jo00291a016
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Cyclopropane unravelling of cyclopropanes and halocyclopropanes, prepared by cyclopropanation of 2,6,6-trimethyl-l-((trimethylsilyl)oxy)cycloheptene and 2-methyl-5-isopropyl-l-((trimethylsilyl)oxy)cyclohexene, is described. Solvolysis, halogenolysis, and protolysis of the cyclopropanes are discussed, and methods of facile synthesis of α-(halomethyl)cycloalkanones are introduced. © 1990, American Chemical Society. All rights reserved.
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页码：1185 / 1193
页数：9
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