REDUCTION OF NITRIC-OXIDE TO NITROUS-OXIDE BY COBALT PORPHYRINS AND CORRINS

被引：4
|
作者：
POTTER, WT [1 ]
CHO, J [1 ]
SUBLETTE, KL [1 ]
机构：
[1] UNIV TULSA,DEPT CHEM ENGN,TULSA,OK 74104
来源：
FUEL PROCESSING TECHNOLOGY | 1994年 / 40卷 / 2-3期
关键词：
COBALT-CENTERED CORRIN; COBALT-CENTERED PORPHYRIN; DITHIOTHRITOL; NITRIC OXIDE REDUCTION; NITROUS OXIDE;
D O I：
10.1016/0378-3820(94)90158-9
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The reduction of nitric oxide (NO) to nitrous oxide (N2O) by dithiothreitol in the presence of cobalt-centered corrin and porphyrin are presented. Reactions were monitored directly using Fourier transform infrared (FTIR) spectroscopy of vapor phase spectra. Reaction rates were two-fold faster for cobalt corrin than cobalt-centered porphyrins. The stoichiometry showed loss of two NO molecules per N2O generation.
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页码：355 / 360
页数：6
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