FINAL-STATE INTERACTIONS IN COLLISIONS OF AN ATOM AND A DIATOMIC MOLECULE

被引:7
作者
MILLER, WH
机构
[1] Department of Chemistry, Harvard University, Cambridge, MA
关键词
D O I
10.1063/1.1671146
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The distorted-wave Born approximation (DWBA) with a semiclassical (WKB) description of relative translational motion is used to characterize final-state interactions in the collision of an atom with a diatomic molecule. The resulting cross section is found to be the product of one factor that varies slowly with energy and another which characterizes the final-state interaction. This latter factor, containing the resonant-type of energy dependence, is determined solely by the distorting potential, being independent of the interaction producing the given transition. Simple physical interpretations and useful extensions are obtained by employing the concept of time delay.
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页码:931 / &
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