LI4[FEN2] - A NITRIDOFERRATE(II) WITH ANIONS ISOSTERIC WITH CO2 - A DEFECT VARIANT OF THE LI3N TYPE-STRUCTURE

被引：34

作者：

GUDAT, A ^{[1
]}

KNIEP, R ^{[1
]}

RABENAU, A ^{[1
]}

机构：

[1] TH DARMSTADT,EDUARD ZINTL INST,W-6100 DARMSTADT,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 02期

关键词：

D O I：

10.1002/anie.199101991

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The continual place-changing of iron atoms in the mixed crystal phases of composition Li4Fe1.04N2, during which the slightly corrigated Li2N layers are maintained, leads in a topotactic reaction to the formation of Li4[FeN2]. This presumably metastable nitridoferrate(II) is one of the lesser known nitridoferrates. Li4[FeN2] crystallizes in a defect variant of the Li3N structure (Li2Fe0.5-square-0.5N), in which Li2N layers are bound by linearly coordinated Fe(II) centers.

引用

页码：199 / 200

页数：2

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