NMR BEHAVIOR AND CRYSTAL-STRUCTURE OF TRI-TER-BUTYLPHOSPHINEALLYLCHLOROPLATINUM(II)

被引：21

作者：

CARTURAN, G ^{[1
]}

BELLUCO, U ^{[1
]}

DELPRA, A ^{[1
]}

ZANOTTI, G ^{[1
]}

机构：

[1] UNIV PADUA,CTR STUDIO BIOPOLIMERI,I-35100 PADUA,ITALY

来源：

INORGANICA CHIMICA ACTA | 1979年 / 33卷 / 02期

关键词：

D O I：

10.1016/S0020-1693(00)89469-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The NMR behaviour of the title compound in CDCl3 solution is reported and discussed in terms of the allyl asymmetry induced by the difference in bonding modes between P(t-butyl)3 and Cl-. The X-ray structure determination shows the presence of four possible orientation of the allyl group in the molecule. © 1979.

引用

页码：155 / 160

页数：6

共 42 条

[1] DYNAMIC STEREOCHEMISTRY OF SOME PI-ALLYLPALLADIUM COMPOUNDS [J].

ALEXANDER, CW ;

JACKSON, WR ;

SPRATT, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1970, 92 (16) :4990-+

[2]

[Anonymous], 1974, INT TABLES XRAY CRYS, VIV

[3] TRANS-INFLUENCE - ITS MEASUREMENT AND SIGNIFICANCE [J].

APPLETON, TG ;

CLARK, HC ;

MANZER, LE .

COORDINATION CHEMISTRY REVIEWS, 1973, 10 (3-4) :335-422

[4] EVIDENCE FOR RESTRICTED ROTATION OF PT-P BOND OF [NU3-C3H5PT[P(C6H11)3]2]+PF6- [J].

ATTIG, TG ;

CLARK, HC .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1975, 94 (03) :C49-C52

[5] ALLYL-PLATINUM COMPLEXES - SYNTHESIS FROM BIS(CYCLO-OCTA-1,5-DIENE)PLATINUM AND THEIR DYNAMIC BEHAVIOR IN SOLUTION [J].

BOAG, NM ;

GREEN, M ;

SPENCER, JL ;

GORDON, F ;

STONE, A .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1977, 127 (02) :C51-C54

[6] SYNTHESIS OF NOVEL SIGMA-ALLYL PLATINUM(II) COMPLEXES [J].

CARTURAN, G ;

SCRIVANTI, A ;

BELLUCO, U .

INORGANICA CHIMICA ACTA, 1977, 21 (01) :103-108

[7] LIGAND-INDUCED FLUXIONALITY IN SOME ETA3-ALLYLPLATINUM(II) COMPLEXES CONTAINING CHELATING LIGANDS - ISOLATION OF DYNAMIC 1-1 ADDUCTS [J].

CLARK, HC ;

JABLONSKI, CR .

INORGANIC CHEMISTRY, 1975, 14 (07) :1518-1526

[8] CHEMISTRY OF METAL HYDRIDES .13. INSERTION AND ISOMERIZATION REACTIONS OF ALLYLIC COMPOUNDS WITH CATIONIC PLATINUM(II)-HYDRIDO COMPLEXES [J].

CLARK, HC ;

KUROSAWA, H .

INORGANIC CHEMISTRY, 1973, 12 (02) :357-362

[9] PI-ALLYL-METAL COMPOUNDS [J].

CLARKE, HL .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1974, 80 (02) :155-173

[10] STEREOCHEMICALLY NONRIGID ORGANOMETALLIC COMPOUNDS .4. SOME OBSERVATIONS ON PI-ALLYLIC COMPLEXES [J].

COTTON, FA ;

FALLER, JW ;

MUSCO, A .

INORGANIC CHEMISTRY, 1967, 6 (01) :179-&

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