DYNAMIC SOLVENT EFFECTS IN ADIABATIC ELECTRON-TRANSFER REACTIONS - ROLE OF TRANSLATIONAL MODES

被引：38
作者：
BAGCHI, B
CHANDRA, A
FLEMING, GR
机构：
[1] UNIV CHICAGO,DEPT CHEM,CHICAGO,IL 60637
[2] UNIV CHICAGO,JAMES FRANCK INST,CHICAGO,IL 60637
来源：
JOURNAL OF PHYSICAL CHEMISTRY | 1990年 / 94卷 / 13期
关键词：
D O I：
10.1021/j100376a001
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A molecular theory of the dynamic solvent effects on an outer-sphere adiabatic electron transfer reaction is presented. The theory properly includes the role of the microscopic correlations present in a dense dipolar solvent in the dynamics of an electron-transfer reaction. The theory predicts that the translational modes of the solvent, hitherto neglected in most discussions on electron-transfer reactions, can significantly enhance the rate of an adiabatic electron-transfer reaction. © 1990 American Chemical Society.
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页码：5197 / 5200
页数：4
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