INTERACTION PARAMETERS FOR KAYS PSEUDOCRITICAL TEMPERATURE

被引：15
作者：
BARNER, HE
QUINLAN, CW
机构：
[1] M. W. Kellogg Co., Piscataway
来源：
INDUSTRIAL & ENGINEERING CHEMISTRY PROCESS DESIGN AND DEVELOPMENT | 1969年 / 8卷 / 03期
关键词：
D O I：
10.1021/i260031a018
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Empirical binary interaction parameters for Kay's pseudocritical temperature are presented for a wide variety of pairs of substances. The interaction terms lead to more reliable pseudocritical temperatures which, in turn, may be used to define pseudocritical pressures according to the scheme recommended by Prausnitz and Gunn. The success of the proposed pseudocritical rule is illustrated for the calculation of density and enthalpy in several binary systems. The method may be readily extended to multicomponent systems. © 1969, American Chemical Society. All rights reserved.
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页码：407 / &
相关论文
共 14 条
[1]   VAPOR-LIQUID EQUILIBRIA AT HIGH PRESSURES . VAPOR-PHASE FUGACITY COEFFICIENTS IN NONPOLAR AND QUANTUM-GAS MIXTURES [J].
CHUEH, PL ;
PRAUSNITZ, JM .
INDUSTRIAL & ENGINEERING CHEMISTRY FUNDAMENTALS, 1967, 6 (04) :492-+
[2]   COMPRESSIBILITIES OF GAS MIXTURES [J].
JOFFE, J .
INDUSTRIAL AND ENGINEERING CHEMISTRY, 1947, 39 (07) :837-838
[3]   FUGACITY COEFFICIENTS IN GAS MIXTURES CONTAINING LIGHT HYDROCARBONS AND CARBON DIOXIDE [J].
JOFFE, J ;
ZUDKEVIT.D .
INDUSTRIAL & ENGINEERING CHEMISTRY FUNDAMENTALS, 1966, 5 (04) :455-&
[4]  
JOFFE J, 1967, CHEM ENGNG PROGR S S, V63, P43
[5]   Liquid-vapor phase equilibrium relations in ethane-n-heptane system [J].
Kay, WB .
INDUSTRIAL AND ENGINEERING CHEMISTRY, 1938, 30 :459-465
[6]  
MATHER AE, 1967, THESIS U MICHIGAN
[7]   THE VOLUMETRIC AND THERMODYNAMIC PROPERTIES OF FLUIDS .5. 2 COMPONENT SOLUTIONS [J].
PITZER, KS ;
HULTGREN, GO .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (18) :4793-4796
[8]   THE VOLUMETRIC AND THERMODYNAMIC PROPERTIES OF FLUIDS .2. COMPRESSIBILITY FACTOR, VAPOR PRESSURE AND ENTROPY OF VAPORIZATION [J].
PITZER, KS ;
LIPPMANN, DZ ;
CURL, RF ;
HUGGINS, CM ;
PETERSEN, DE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1955, 77 (13) :3433-3440
[9]  
PITZER KSX, 1958, IND ENG CHEM, V50, P265
[10]   VOLUMETRIC PROPERTIES OF NONPOLAR GASEOUS MIXTURES [J].
PRAUSNITZ, JM ;
GUNN, RD .
AICHE JOURNAL, 1958, 4 (04) :430-435
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