PREPARATION OF HIGH-PURITY VITREOUS B2S3

被引：50

作者：

MARTIN, SW

BLOYER, DR

机构：

[1] Department of Materials Science and Engineering, Iowa State University of Science and Technology, Ames, Iowa

来源：

JOURNAL OF THE AMERICAN CERAMIC SOCIETY | 1990年 / 73卷 / 11期

关键词：

boron; impurities; preparation; sulfides; vitreous materials;

D O I：

10.1111/j.1151-2916.1990.tb06480.x

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Preparation schemes for high‐purity vitreous B2S3 (v‐B2S3) with a S:B ratio of 1.478 ± 0.032 are described. Preparation schemes reported in the literature are shown by very sensitive FT‐IR measurements to yield v‐B2S3 with significant oxygen contamination. Through extreme care taken in carbonizing silica reaction tubes and through the use of very high purity starting materials, oxygen contamination of less than 1% has been achieved. The IR spectrum for very pure v‐B2S3 contains only two absorption bands. Copyright © 1990, Wiley Blackwell. All rights reserved

引用

页码：3481 / 3485

页数：5

共 28 条

[1]

BRAY PJ, 1960, MOD ASPECT VITR, V1, pCH5

[2] FAST LI+ ION-TRANSPORT IN IODINE-THIOBORATE GLASSES [J].

BURCKHARDT, W ;

MAKYTA, M ;

LEVASSEUR, A ;

HAGENMULLER, P .

MATERIALS RESEARCH BULLETIN, 1984, 19 (08) :1083-1089

[3]

CHEN H, 1969, THESIS KANSAS STATE

[4] HIGH MOLECULAR WEIGHT BORON SULFIDES .5. VAPORIZATION BEHAVIOR OF BORON-SULFUR SYSTEM [J].

CHEN, HY ;

GILLES, PW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1970, 92 (08) :2309-+

[5]

COSTEANU D, 1913, CR HEBD ACAD SCI, V157, P934

[6]

DEIRCKS H, 1977, ANGEW CHEM INT EDIT, V16, P313

[7] NMR-STUDIES OF THE SYSTEM B-S-TL [J].

ECKERT, H ;

MULLERWARMUTH, W ;

HAMANN, W ;

KREBS, B .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 1984, 65 (01) :53-62

[8] VIBRATIONAL-SPECTRA AND THE STRUCTURE OF PURE VITREOUS B2O3 [J].

GALEENER, FL ;

LUCOVSKY, G ;

MIKKELSEN, JC .

PHYSICAL REVIEW B, 1980, 22 (08) :3983-3990

[9]

GAUTHIER P, 1899, ANN CHIM PHYS, V18, P352

[10]

GEISSBERGER AE, 1982, STRUCTURE NONCRYSTAL, P381

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