THE OXIDATION OF CO OVER RU(001) AT HIGH-PRESSURES - CO RESIDENCE TIMES AND REACTION-MECHANISM

被引：12

作者：

HOFFMANN, FM ^{[1
]}

WEISEL, MW ^{[1
]}

PEDEN, CHF ^{[1
]}

机构：

[1] SANDIA NATL LABS,ALBUQUERQUE,NM 87185

来源：

JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA | 1990年 / 54卷

基金：

美国能源部;

关键词：

D O I：

10.1016/0368-2048(90)80270-K

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

In order to elucidate the unusual catalytic behavior of ruthenium in the oxidation of CO, we have studied this reaction on a Ru(001) single crystal surface at high pressures with in-situ Fourier Transform-Infrared Reflection Absorption Spectroscopy (FT-IRAS). From the measurement of the steady-state surface coverages we are able to obtain estimates of mean residence times of the reactants. Under highly oxidizing conditions, where an O-(1 x 1) layer is present at the surface and the CO2 formation rate exhibits a maximum, we find CO residence times in the order of 10(-12) s. This suggests that the oxidation of CO may occur by direct reaction between gas-phase CO and chemisorbed oxygen atoms.

引用

页码：779 / 786

页数：8

共 15 条

[1]

[Anonymous], 1979, ADV CATAL, DOI DOI 10.1016/S0360-0564(08)60133-9

[2]

BERLOWITZ PJ, 1988, J PHYS CHEM, V92

[3] STUDIES ON SELF-SUSTAINED REACTION-RATE OSCILLATIONS .2. THE ROLE OF CARBON AND OXIDES IN THE OSCILLATORY OXIDATION OF CARBON-MONOXIDE ON PLATINUM [J].