CaF2 nanoparticles: Synthesis and characterization

被引：26
作者：
Tahvildari, K. [1 ]
Pour, M. Esmaeili [1 ]
Ghammamy, Sh. [2 ]
Nabipour, H. [2 ]
机构：
[1] Islamic Azad Univ, Dept Chem, North Tehran Branch, Tehran, Iran
[2] Islamic Azad Univ, Dept Chem, Takestan Branch, Takesatn, Iran
来源：
INTERNATIONAL JOURNAL OF NANO DIMENSION | 2012年 / 2卷 / 04期
关键词：
Synthesis; Characterization; Nanoparticles; Calcium fluoride;
D O I：
10.7508/ijnd.2011.04.008
中图分类号：
TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
The aim of the present study was to prepare nano-sized calcium fluoride (CaF2). Calcium fluoride nanoparticles were synthesized by CaCl2 center dot 6H(2)O and ammonium fluoride. Nanoparticles were synthesized by co-precipitation method. The synthesized nanocrystals were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM). The crystallite size estimated using Scherer's formula was found to be in the range of 20-30nm for nanocrystals synthesized by this method. The morphological features as studied using SEM revealed that the nanoparticles were agglomerated, crispy with porous.
引用
收藏
页码：269 / 273
页数：5
相关论文
共 28 条
  • [1] Synthesis and optical characterizations of Yb-doped CaF2 ceramics
    Aubry, P.
    Bensalah, A.
    Gredin, P.
    Patriarche, G.
    Vivien, D.
    Mortier, M.
    [J]. OPTICAL MATERIALS, 2009, 31 (05) : 750 - 753
  • [2] Synthesis and optical characterizations of undoped and rare-earth-doped CaF2 nanoparticles
    Bensalah, A.
    Mortier, M.
    Patriarche, G.
    Gredin, P.
    Vivien, D.
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 2006, 179 (08) : 2636 - 2644
  • [3] Higher-order organization by mesoscale self-assembly and transformation of hybrid nanostructures
    Cölfen, H
    Mann, S
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (21) : 2350 - 2365
  • [4] Role of organic additives in the sol-gel synthesis of porous CaF2 anti-reflective coatings
    Fujihara, S
    Kadota, Y
    Kimura, T
    [J]. JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2002, 24 (02) : 147 - 154
  • [5] X-RAY-DIFFRACTION INVESTIGATIONS OF CAF2 AT HIGH-PRESSURE
    GERWARD, L
    OLSEN, JS
    STEENSTRUP, S
    MALINOWSKI, M
    ASBRINK, S
    WASKOWSKA, A
    [J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1992, 25 : 578 - 581
  • [6] Flame synthesis of calcium-, strontium-, barium fluoride nanoparticles and sodium chloride
    Grass, RN
    Stark, WJ
    [J]. CHEMICAL COMMUNICATIONS, 2005, (13) : 1767 - 1769
  • [7] Luminescence studies of the rare earth ions-doped CaF2 and MgF2 films for wavelength conversion
    Hong, BC
    Kawano, K
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2006, 408 : 838 - 841
  • [8] Syntheses of CaF2:Eu nanoparticles and the modified reducing TCRA treatment to divalent Eu ion
    Hong, Byung-Chul
    Kawano, Katsuyasu
    [J]. OPTICAL MATERIALS, 2008, 30 (06) : 952 - 956
  • [9] Reduction of Eu2+-activated nanoparticles by unique TCRA treatment
    Hong, Byung-Chul
    Kawano, Katsuyasu
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2008, 451 (1-2) : 276 - 279
  • [10] A study of nanocrystalline NiFe2O4 in a silica matrix
    Huang, XH
    Chen, ZH
    [J]. MATERIALS RESEARCH BULLETIN, 2005, 40 (01) : 105 - 113
123