SYNTHESIS OF PERFLUOROALKYL CARBOXYLIC-ACIDS BY REACTION OF PERFLUOROALKYL IODIDES WITH ELECTROGENERATED SUPEROXIDE ION

被引：21

作者：

DAPREMONTAVIGNON, C

CALAS, P

COMMEYRAS, A

AMATORE, C

机构：

[1] ECOLE NORMALE SUPER,CHIM LAB,URA 1110,24 RUE LHOMOND,F-75231 PARIS 05,FRANCE

[2] UNIV MONTPELLIER 2,F-34095 MONTPELLIER 5,FRANCE

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1991年 / 51卷 / 03期

关键词：

D O I：

10.1016/S0022-1139(00)80191-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The electrogenerated superoxide ion O2-degrees- is shown to react with perfluoroalkyliodides to afford F-alkyl carboxylic acids. A mechanism is proposed on the basis of the results obtained in preparative experiments and by cyclic voltammetry.

引用

页码：357 / 379

页数：23

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