Crystal structure of 2,2 '-({[2-(tritylsulfanyl)benzyl]azanediyl}bis(ethane-2,1diyl))bis(isoindoline-1,3-dione)

被引：1

作者：

Floerke, Ulrich ^{[1
]}

Neuba, Adam ^{[1
]}

Ortmeyer, Jochen ^{[1
]}

Henkel, Gerald ^{[1
]}

机构：

[1] Univ Paderborn, Warburger Str 100, D-33098 Paderborn, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷

关键词：

crystal structure; tripodal ligands; phthalimide; hydrogen bonding;

D O I：

10.1107/S1600536814015554

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the structure of the title compound, C46H37N3O4S, the planes of the two isoindoline units make a dihedral angle of 77.86 (3)degrees. The dihedral angles between the benzyl plane and the isoindoline units are 79.56 (4) and 3.74 (9)degrees. The geometry at the S atom shows a short [1.7748 (17) angstrom] S-Cbenzyl and a long [1.8820 (15) angstrom] S-Ctrityl bond and the C-S-C angle is 108.40 (7)degrees. N-C bond lengths around the azane N atom are in the range 1.454 (2)-1.463 (2) angstrom. he crystal packing exhibts two rather 'non-classical' C-H center dot center dot center dot O hydrogen bonds that result in stacking of the molecules along the a as well as the b axis and give rise to columnar sub-structures.

引用

页码：O895 / +

页数：12

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