AMINO-ACID DERIVED HOMOCHIRAL POLYMERS VIA RING-OPENING METATHESIS POLYMERIZATION

被引：44

作者：

COLES, MP

GIBSON, VC

MAZZARIOL, L

NORTH, M

TEASDALE, WG

WILLIAMS, CM

ZAMUNER, D

机构：

[1] UNIV DURHAM,DEPT CHEM,DURHAM DH1 3LE,ENGLAND

[2] UNIV COLL N WALES,DEPT CHEM,BANGOR LL57 2UW,GWYNEDD,WALES

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 21期

关键词：

D O I：

10.1039/c39940002505

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Homochiral norbornene monomers derived from amino acids undergo ring-opening metathesis polymerisation with [Mo(=CHCMe(2)Ph)(=NC6H3Pr2i-2,6)(OBu(t))(2)] to give homochiral polymers with narrow molecular mass distributors.

引用

页码：2505 / 2506

页数：2

共 8 条

[1] POLYMERIZATION OF FUNCTIONALIZED NORBORNENES EMPLOYING MO(CH-T-BU)(NAR)(O-T-BU)2 AS THE INITIATOR [J].

BAZAN, GC ;

SCHROCK, RR ;

CHO, HN ;

GIBSON, VC .

MACROMOLECULES, 1991, 24 (16) :4495-4502

[2] LIVING RING-OPENING METATHESIS POLYMERIZATION OF 2,3-DIFUNCTIONALIZED NORBORNADIENES BY MO(CH-TERT-BU)(N-2,6-C6H3-ISO-PR2)(O-TERT-BU)2 [J].

BAZAN, GC ;

KHOSRAVI, E ;

SCHROCK, RR ;

FEAST, WJ ;

GIBSON, VC ;

OREGAN, MB ;

THOMAS, JK ;

DAVIS, WM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (23) :8378-8387

[3] A REMARKABLE ANCILLARY LIGAND EFFECT IN LIVING RING-OPENING METATHESIS POLYMERIZATION [J].

FEAST, WJ ;

GIBSON, VC ;

MARSHALL, EL .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (16) :1157-1158

[4]

FEAST WJ, 1989, CHEM METAL CARBON BO, V5

[5] POLYMER SYNTHESIS AND ORGANOTRANSITION METAL CHEMISTRY [J].

GRUBBS, RH ;

TUMAS, W .

SCIENCE, 1989, 243 (4893) :907-915

[6] SYNTHESIS OF CHIRAL MOLYBDENUM ROMP INITIATORS AND ALL-CIS HIGHLY TACTIC POLY(2,3-(R)2NORBORNADIENE) (R = CF3 OR CO2ME) [J].

MCCONVILLE, DH ;

WOLF, JR ;

SCHROCK, RR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (10) :4413-4414

[7] ROTATIONAL ISOMERS OF MO(VI) ALKYLIDENE COMPLEXES AND CIS-TRANS POLYMER STRUCTURE - INVESTIGATIONS IN RING-OPENING METATHESIS POLYMERIZATION [J].

OSKAM, JH ;

SCHROCK, RR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (25) :11831-11845

[8] LIVING RING-OPENING METATHESIS POLYMERIZATION CATALYZED BY WELL-CHARACTERIZED TRANSITION-METAL ALKYLIDENE COMPLEXES [J].

SCHROCK, RR .

ACCOUNTS OF CHEMICAL RESEARCH, 1990, 23 (05) :158-165

← 1 →