BETA-HYDROXYSULFOXIMINES IN THE CATALYZED ENANTIOSELECTIVE REDUCTION OF KETONES WITH BORANE

被引：48
|
作者：
BOLM, C
FELDER, M
机构：
[1] Department of Chemistry, University of Basel, CH-4056 Basel
来源：
TETRAHEDRON LETTERS | 1993年 / 34卷 / 38期
关键词：
ASYMMETRIC REDUCTION; SULFOXIMINES; ENANTIOSELECTIVE CATALYSIS;
D O I：
10.1016/S0040-4039(00)61722-7
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Optically active beta-hydroxysulfoximines catalyze the asymmetric borane reduction of ketones affording secondary alcohols in high yields with good enantioselectivities (up to 93% ee).
引用
收藏
页码：6041 / 6044
页数：4
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