OXIDATION AND BIODEGRADABILITY ENHANCEMENT OF 1,4-DIOXANE USING HYDROGEN-PEROXIDE AND OZONE

被引：195
作者：
ADAMS, CD
SCANLAN, PA
SECRIST, ND
机构：
[1] Department of Environmental Systems Engineering, Clemson University, South Carolina 29634, Clemson
[2] Black ' Veatch, Engineers-Architects, Kansas City, MO 64114
来源：
ENVIRONMENTAL SCIENCE & TECHNOLOGY | 1994年 / 28卷 / 11期
关键词：
D O I：
10.1021/es00060a010
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
Ozone in combination with hydrogen peroxide has been shown to effectly oxidize 1,4-dioxane in synthetic solutions representing groundwater or industrial wastewater to more readily biodegradable oxidation products that could be treated using conventional. biological treatment. Bicarbonate alkalinity and competition by 1,3-dioxolane and 2-methyl-1,3-dioxolane were found to increase the oxidant dosages required for 1,4-dioxane oxidation. The results of this study suggest that anaerobic pretreatment prior to advanced oxidation may be a viable means of reducing the ozone and hydrogen peroxide dosages required for biodegradability enhancement.
引用
收藏
页码：1812 / 1818
页数：7
相关论文
共 49 条
[41]   BIODEGRADABILITY AND GAC ADSORBABILITY OF MICROPOLLUTANTS BY PREOZONATION [J].
SOMIYA, I ;
YAMADA, H ;
NOZAWA, E ;
MOHRI, M .
OZONE-SCIENCE & ENGINEERING, 1986, 8 (01) :11-26
[42]   DECOMPOSITION OF OZONE IN WATER IN THE PRESENCE OF ORGANIC SOLUTES ACTING AS PROMOTERS AND INHIBITORS OF RADICAL CHAIN REACTIONS [J].
STAEHELIN, J ;
HOIGNE, J .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1985, 19 (12) :1206-1213
[43]   DECOMPOSITION OF OZONE IN WATER - RATE OF INITIATION BY HYDROXIDE IONS AND HYDROGEN-PEROXIDE [J].
STAEHELIN, J ;
HOIGNE, J .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1982, 16 (10) :676-681
[44]   EFFECT OF OZONE TREATMENT UPON BIODEGRADABILITY OF WATER-SOLUBLE POLYMERS [J].
SUZUKI, J ;
HUKUSHIMA, K ;
SUZUKI, S .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1978, 12 (10) :1180-1183
[45]  
THOMAS JK, 1966, T FARADAY SOC, V61, P702
[46]   THE EFFECTS OF OZONATION, BIOLOGICAL FILTRATION AND DISTRIBUTION ON THE CONCENTRATION OF EASILY ASSIMILABLE ORGANIC-CARBON (AOC) IN DRINKING-WATER [J].
VANDERKOOIJ, D ;
HIJNEN, WAM ;
KRUITHOF, JC .
OZONE-SCIENCE & ENGINEERING, 1989, 11 (03) :297-311
[47]  
Watt R. D., 1985, Journal of the Water Pollution Control Federation, V57, P157
[48]   PULSE RADIOLYSIS OF DEAERATED AQUEOUS CARBONATE SOLUTIONS .I. TRANSIENT OPTICAL SPECTRUM AND MECHANISM .2. PK FOR OH RADICALS [J].
WEEKS, JL ;
RABANI, J .
JOURNAL OF PHYSICAL CHEMISTRY, 1966, 70 (07) :2100-&
[49]   ENHANCEMENT OF TOXICITY AND ENZYME-REPRESSING ACTIVITY OF PARA-DIOXANE BY CHLORINATION - STEREOSELECTIVE EFFECTS [J].
WOO, YT ;
NEUBURGER, BJ ;
ARCOS, JC ;
ARGUS, MF ;
NISHIYAMA, K ;
GRIFFIN, GW .
TOXICOLOGY LETTERS, 1980, 5 (01) :69-75
12345