PALLADIUM(0)-CATALYZED SUBSTITUTION OF ALLYLIC SUBSTRATES IN AN AQUEOUS-ORGANIC MEDIUM

被引：82
作者：
BLART, E
GENET, JP
SAFI, M
SAVIGNAC, M
SINOU, D
机构：
[1] ECOLE NATL SUPER CHIM PARIS,CNRS,SYNTH ORGAN LAB,F-75231 PARIS,FRANCE
[2] UNIV LYON 1,ESCIL,CNRS,SYNTH ASYMETR LAB,F-69622 VILLEURBANNE,FRANCE
来源：
TETRAHEDRON | 1994年 / 50卷 / 02期
关键词：
D O I：
10.1016/S0040-4020(01)80772-9
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A palladium(0)-water soluble catalyst prepared in situ from palladium acetate and the sulfonated triphenyl phosphine P(C6H4-m-SO3Na)(3) (or tppts) is an efficient catalyst for allylic substitution with various carbon and heteronucleophiles in an aqueous-organic medium, allowing a very easy separation of the product(s) and the recycling of the catalyst.
引用
收藏
页码：505 / 514
页数：10
相关论文
共 53 条
  • [21] ALKYLATION OF ALPHA-NITROACETATES CATALYZED BY ETA-3 COMPLEXES OF PALLADIUM
    GENET, JP
    FERROUD, D
    [J]. TETRAHEDRON LETTERS, 1984, 25 (33) : 3579 - 3582
  • [22] A PRACTICAL SYNTHESIS OF ALPHA-AMINOPHOSPHONIC ACIDS
    GENET, JP
    UZIEL, J
    PORT, M
    TOUZIN, AM
    ROLAND, S
    THORIMBERT, S
    TANIER, S
    [J]. TETRAHEDRON LETTERS, 1992, 33 (01) : 77 - 80
  • [23] GOLDESKI SA, 1991, COMPREHENSIVE ORGANI, V4, P585
  • [24] SYNTHESIS OF ALLYL ARYL SULFIDES BY PALLADIUM(0)-MEDIATED ALKYLATION OF THIOLS
    GOUX, C
    LHOSTE, P
    SINOU, D
    [J]. TETRAHEDRON LETTERS, 1992, 33 (52) : 8099 - 8102
  • [25] GOUX C, 1992, SYNLETT, P725
  • [26] SELECTIVE HYDROGENATION OF ALPHA,BETA-UNSATURATED ALDEHYDES IN AQUEOUS ORGANIC 2-PHASE SOLVENT SYSTEMS USING RUTHENIUM OR RHODIUM COMPLEXES OF SULFONATED PHOSPHINES
    GROSSELIN, JM
    MERCIER, C
    ALLMANG, G
    GRASS, F
    [J]. ORGANOMETALLICS, 1991, 10 (07) : 2126 - 2133
  • [27] Heck R. F., 1985, PALLADIUM REAGENTS O
  • [28] REGIOCONTROLLED AND STEREOCONTROLLED SYNTHESIS OF ALLYLIC PARA-TOLYL SULFONES CATALYZED BY PALLADIUM (0) COMPLEX
    INOMATA, K
    YAMAMOTO, T
    KOTAKE, H
    [J]. CHEMISTRY LETTERS, 1981, (10) : 1357 - 1360
  • [29] CATALYSIS BY WATER-SOLUBLE PHOSPHINE COMPLEXES OF TRANSITION-METAL IONS IN AQUEOUS AND 2-PHASE MEDIA
    JOO, F
    TOTH, Z
    [J]. JOURNAL OF MOLECULAR CATALYSIS, 1980, 8 (04): : 369 - 383
  • [30] USE OF WATER-SOLUBLE LIGANDS IN HOMOGENEOUS CATALYSIS
    KALCK, P
    MONTEIL, F
    [J]. ADVANCES IN ORGANOMETALLIC CHEMISTRY, 1992, 34 : 219 - 284
123456