PALLADIUM(0)-CATALYZED SUBSTITUTION OF ALLYLIC SUBSTRATES IN AN AQUEOUS-ORGANIC MEDIUM

被引：82
作者：
BLART, E
GENET, JP
SAFI, M
SAVIGNAC, M
SINOU, D
机构：
[1] ECOLE NATL SUPER CHIM PARIS,CNRS,SYNTH ORGAN LAB,F-75231 PARIS,FRANCE
[2] UNIV LYON 1,ESCIL,CNRS,SYNTH ASYMETR LAB,F-69622 VILLEURBANNE,FRANCE
来源：
TETRAHEDRON | 1994年 / 50卷 / 02期
关键词：
D O I：
10.1016/S0040-4020(01)80772-9
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A palladium(0)-water soluble catalyst prepared in situ from palladium acetate and the sulfonated triphenyl phosphine P(C6H4-m-SO3Na)(3) (or tppts) is an efficient catalyst for allylic substitution with various carbon and heteronucleophiles in an aqueous-organic medium, allowing a very easy separation of the product(s) and the recycling of the catalyst.
引用
收藏
页码：505 / 514
页数：10
相关论文
共 53 条
[21]   ALKYLATION OF ALPHA-NITROACETATES CATALYZED BY ETA-3 COMPLEXES OF PALLADIUM [J].
GENET, JP ;
FERROUD, D .
TETRAHEDRON LETTERS, 1984, 25 (33) :3579-3582
[22]   A PRACTICAL SYNTHESIS OF ALPHA-AMINOPHOSPHONIC ACIDS [J].
GENET, JP ;
UZIEL, J ;
PORT, M ;
TOUZIN, AM ;
ROLAND, S ;
THORIMBERT, S ;
TANIER, S .
TETRAHEDRON LETTERS, 1992, 33 (01) :77-80
[23]  
GOLDESKI SA, 1991, COMPREHENSIVE ORGANI, V4, P585
[24]   SYNTHESIS OF ALLYL ARYL SULFIDES BY PALLADIUM(0)-MEDIATED ALKYLATION OF THIOLS [J].
GOUX, C ;
LHOSTE, P ;
SINOU, D .
TETRAHEDRON LETTERS, 1992, 33 (52) :8099-8102
[25]  
GOUX C, 1992, SYNLETT, P725
[26]   SELECTIVE HYDROGENATION OF ALPHA,BETA-UNSATURATED ALDEHYDES IN AQUEOUS ORGANIC 2-PHASE SOLVENT SYSTEMS USING RUTHENIUM OR RHODIUM COMPLEXES OF SULFONATED PHOSPHINES [J].
GROSSELIN, JM ;
MERCIER, C ;
ALLMANG, G ;
GRASS, F .
ORGANOMETALLICS, 1991, 10 (07) :2126-2133
[27]  
Heck R. F., 1985, PALLADIUM REAGENTS O
[28]   REGIOCONTROLLED AND STEREOCONTROLLED SYNTHESIS OF ALLYLIC PARA-TOLYL SULFONES CATALYZED BY PALLADIUM (0) COMPLEX [J].
INOMATA, K ;
YAMAMOTO, T ;
KOTAKE, H .
CHEMISTRY LETTERS, 1981, (10) :1357-1360
[29]   CATALYSIS BY WATER-SOLUBLE PHOSPHINE COMPLEXES OF TRANSITION-METAL IONS IN AQUEOUS AND 2-PHASE MEDIA [J].
JOO, F ;
TOTH, Z .
JOURNAL OF MOLECULAR CATALYSIS, 1980, 8 (04) :369-383
[30]   USE OF WATER-SOLUBLE LIGANDS IN HOMOGENEOUS CATALYSIS [J].
KALCK, P ;
MONTEIL, F .
ADVANCES IN ORGANOMETALLIC CHEMISTRY, 1992, 34 :219-284
123456