ENHANCED STEREOSELECTIVITY IN AQUEOUS INTRAMOLECULAR HETERO-DIELS-ALDER CYCLOADDITION OF CHIRAL ACYLNITROSO COMPOUNDS

被引：31

作者：

NARUSE, M ^{[1
]}

AOYAGI, S ^{[1
]}

KIBAYASHI, C ^{[1
]}

机构：

[1] TOKYO COLL PHARM,HACHIOJI,TOKYO 19203,JAPAN

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 04期

关键词：

D O I：

10.1016/S0040-4039(00)75847-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In an aqueous medium, intramolecular hetero Diels-Alder cycloadditions of the chiral acylnitroso compounds, generated from the chiral hydroxamic acids by in situ periodate oxidation, shows a pronounced enhancement of the trans selectivity compared with the results obtained by employing nonaqueous conditions.

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页码：595 / 598

页数：4

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