ACID-BASE PROPERTIES OF GLASS SURFACES

被引：89

作者：

FOWKES, FM ^{[1
]}

DWIGHT, DW ^{[1
]}

COLE, DA ^{[1
]}

HUANG, TC ^{[1
]}

机构：

[1] PPG IND INC,PITTSBURGH,PA 15230

来源：

JOURNAL OF NON-CRYSTALLINE SOLIDS | 1990年 / 120卷 / 1-3期

关键词：

D O I：

10.1016/0022-3093(90)90190-W

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

The adhesion of polymers to inorganic oxides such as glass is very dependent on acid-base interactions between the acidic or basic surface sites of the glass and the basic or acidic functional sites of the polymer. This paper reviews the principles of such interactions, methods of measuring the acidity or basicity of surface sites, and the enhanced mechanical properties of glass-reinforced polymer composites resulting from interfacial acid-base complexation. A new study is presented of the acid-base properties of fiberglass and of surface treatments with silane coupling agents and polyvinyl acetate. It illustrates calorimetric titration methods for assessing surface acidity and basicity, and correlates these findings with angular-dependent X-ray photoelectron spectroscopy (ADXPS). © 1990.

引用

页码：47 / 60

页数：14

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