RU3(CO)12/2,2'-BIPYRIDINE SUPPORTED ON INORGANIC CARRIERS AS 1-HEXENE HYDROFORMYLATION CATALYSTS

被引：28
作者：
ALVILA, L
PURSIAINEN, J
KIVIAHO, J
PAKKANEN, TA
KRAUSE, O
机构：
[1] TECH RES CTR FINLAND,CHEM LAB,SF-02151 ESPOO,FINLAND
[2] NESTE LTD,CTR TECHNOL,SF-06101 PORVOO,FINLAND
来源：
JOURNAL OF MOLECULAR CATALYSIS | 1994年 / 91卷 / 03期
关键词：
CARBONYL COMPLEXES; HEXENE; HYDROFORMYLATION; PYRIDINES; RUTHENIUM; SUPPORTED CATALYSTS;
D O I：
10.1016/0304-5102(94)00044-1
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Ru3(CO)12 and 2,2'-bipyridine were supported on various inorganic carriers and used as hydroformylation catalysts. The stability of the catalyst was studied by determining ruthenium contents of hydroformylation products and also by special dissolution tests. Ruthenium was found to dissolve in hydroformylation products (aldehydes and alcohols). However, the nature of the catalyst proved to be mainly heterogeneous.
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页码：335 / 342
页数：8
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