ENTHALPIES OF SOLUTION AND INTERMOLECULAR FORCES - TERT-BUTYL HALIDES IN HYDROXYLIC SOLVENTS

被引：16

作者：

GONCALVES, RMC ^{[1
]}

ALBUQUERQUE, LMPC ^{[1
]}

MARTINS, FEL ^{[1
]}

SIMOES, AMN ^{[1
]}

RAMOS, JJM ^{[1
]}

机构：

[1] Univ Tecn Lisboa, CTR QUIM FIS MOLEC, INST SUPER TECN, P-1096 LISBON, PORTUGAL

来源：

JOURNAL OF PHYSICAL ORGANIC CHEMISTRY | 1992年 / 5卷 / 02期

关键词：

D O I：

10.1002/poc.610050205

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The application of cavity theories of solution and linear solvation energy relationships to the interpretation of enthalpy of solution values of tert-butyl halides in hydroxylic media, measured at 25-degrees-C and infinite dilution, is deserted, in order to define the intermolecular forces acting between solutes and solvents. It is concluded that solvent dipolarity and solvent HBD acidity effects dominate the solution process. An empirical equation relating the enthalpies of solution with selected properties of both solvents and solutes is proposed. New experimental DELTA-H(s)infinity values for tert-butyl iodide in 13 alcohols are reported.

引用

页码：93 / 100

页数：8

共 44 条

[1]

ALLEN G, 1960, POLYMER, V1, P456

[2]

[Anonymous], 1970, REGULAR RELATED SOLU

[3]

[Anonymous], 1987, PROPERTIES GASES LIQ

[4] SOLVENT EFFECTS IN ORGANIC CHEMISTRY .V. MOLECULES IONS AND TRANSITION STATES IN AQUEOUS ETHANOL [J].

ARNETT, EM ;

BENTRUDE, WG ;

BURKE, JJ ;

DUGGLEBY, PM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (07) :1541-+

[5]

Barton A. F. M., 1985, CRC HDB SOLUBILITY P

[6] IMPROVEMENT OF THE APPLICABILITY OF TAFT-KAMLET SOLVENT POLARITY PARAMETERS TO CHEMICAL-REACTIVITY [J].

BEKAREK, V .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1983, (09) :1293-1296

[7] VAN DER WAALS VOLUMES + RADII [J].

BONDI, A .

JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (03) :441-+

[8] STATIC DIELECTRIC-CONSTANT, VISCOSITY, AND STRUCTURE OF PURE ISOMERIC PENTANOLS [J].

DAPRANO, A ;

DONATO, DI ;

AGRIGENTO, V .

JOURNAL OF SOLUTION CHEMISTRY, 1981, 10 (09) :673-680

[9] TEST OF PIEROTTIS THEORY FOR SOLUBILITY OF GASES IN LIQUIDS, BY MEANS OF LITERATURE DATA ON SOLUBILITY AND ENTROPY OF SOLUTION [J].

DELIGNY, CL ;

VANDERVE.NG .

CHEMICAL ENGINEERING SCIENCE, 1972, 27 (02) :391-&

[10]

DESROSIERS NM, 1981, CAN J CHEM, V59, P1

← 1 2 3 4 5 →