SYNTHESIS OF SUBSTITUTED METALLA-AZIRIDINES BY THE REACTION OF C5H5(CO)M-2-CHELATE COMPLEXES (M=MO,W) WITH NUCLEOPHILES

被引：6
作者：
BRUNNER, H
SCHWAGERL, H
WACHTER, J
机构：
[1] Institut für Chemie der Universität Regensburg, Regensburg, D-8400
来源：
CHEMISCHE BERICHTE-RECUEIL | 1979年 / 112卷 / 06期
关键词：
D O I：
10.1002/cber.19791120618
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Die Komplexe [C5H5(CO)2MNN′]Cl (MMo, W) 1a–e und 2a‐c mit fünfgliedrigem Chelatring MNN′ (NN′ =Schiffbase aus 2‐Pyridincarbaldehyd und verschieden Aminen) reagieren mit CH3Li, C6H5Li und p‐R′C6H4MgBr (R′ = H, CH3, OCH3, Cl) zu den neutralen Metalla‐aziridines 3–6. 1H und 13C‐NMR Spektren deuten auf einen stereospezifischen Ablauf der Ringverengung. Copyright © 1979 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim
引用
收藏
页码：2079 / 2086
页数：8
相关论文
共 17 条
[1]   SYNTHESES AND PROPERTIES OF AMINOMETHYL COMPLEXES OF MANGANESE AND RHENIUM [J].
ABEL, EW ;
ROWLEY, RJ .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1975, (11) :1096-1099
[2]   AMINOMETHYLENETETRACARBONYLS OF MANGANESE - X-RAY CRYSTAL-STRUCTURE OF AZIRIDINYLMETHYLTETRACARBONYLMANGANESE [J].
ABEL, EW ;
ROWLEY, RJ ;
MASON, R ;
THOMAS, KM .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1974, (02) :72-73
[3]   ISOCYANIDE INSERTION REACTIONS .2. STRUCTURAL AND DYNAMICAL STEREOCHEMISTRY OF ETA-1-IMINOACYL AND ETA-2-IMINOACYL LIGANDS [J].
ADAMS, RD ;
CHODOSH, DF .
INORGANIC CHEMISTRY, 1978, 17 (01) :41-48
[4]  
BERNAL J, UNPUBLISHED
[5]   OPTICALLY ACTIVE TRANSITION-METAL COMPLEXES .13. OPTICALLY ACTIVE AZOMETHINE DERIVATIVES OF TRICARBONYL(CYCLOPENTADIENYL)MOLYBDENUM AND TUNGSTEN CHLORIDE [J].
BRUNNER, H ;
HERRMANN, WA .
CHEMISCHE BERICHTE-RECUEIL, 1972, 105 (11) :3600-&
[6]   STEREOCHEMISTRY OF SQUARE-PYRAMIDAL COMPOUNDS [J].
BRUNNER, H .
CHEMIE IN UNSERER ZEIT, 1977, 11 (05) :157-164
[7]   MASS SPECTROMETRICAL INVESTIGATIONS OF DICARBONYL(CYCLOPENTADIENYL)(THIOAMIDATO) COMPLEXES OF MOLYBDENUM AND TUNGSTEN [J].
BRUNNER, H ;
MAYER, KK ;
WACHTER, J .
CHEMISCHE BERICHTE-RECUEIL, 1977, 110 (02) :730-736
[8]   OPTICALLY-ACTIVE TRANSITION-METAL COMPLEX .39. STEREOSPECIFIC PHENYL ADDITION TO C2H5(CO)2MO-PYRIDINECARBALDIMINE CATION [J].
BRUNNER, H ;
WACHTER, J .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1976, 113 (04) :C58-C60
[9]   RING CONTRACTION IN REACTION OF CATIONIC C5H5MO(CO)2 CHELATE COMPLEXES WITH METHYLLITHIUM [J].
BRUNNER, H ;
SCHWAGER, H ;
WACHTER, J ;
REISNER, GM ;
BERNAL, I .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1978, 17 (06) :453-454
[10]   OPTICALLY-ACTIVE TRANSITION-METAL COMPLEXES .50. ARYL ROTATION IN THIOAMIDATO-C5H5(CO)2MO COMPLEXES [J].
BRUNNER, H ;
BAUER, E ;
WACHTER, J .
CHEMISCHE BERICHTE-RECUEIL, 1978, 111 (01) :379-387
12