SULPHUR-NITROGEN CHELATING AGENTS .6. 5-COORDINATE AND 6-COORDINATE COMPLEXES OF 3D METAL IONS WITH AN SNN TRIDENTATE LIGAND

Mono-ligand complexes of 6-methylpyrid-2-yl-N-(2′-methylthiophenyl)- methyleneimine (SNSMe) of the type MX2(SNNMe) (M = Mn, Fe, Co, Xi, and Cu; X = Cl, Br, I, or NCS) have been prepared. Infrared data show that in all the complexes the ligand (SNNMe) is tridentate. The electronic and infrared spectra indicate that the complexes of manganese, iron, and cobalt are five-coordinate, whereas the nickel and copper complexes are six-coordinate and polymeric. The complex CO(NO3)2(SNNMe) is six- coordinate and contains one bidentate and one unidentate nitrato group. The bis-ligand complexes [N(SNNMe)2]Y2 (M = Fe, Ni, and Cu; Y = ClO4 or BF4) were also isolated. The iron complex is low-spin (μ 1·5 B.M.) but the magnetic moment of the nickel complex (μ 3·0 B.M.) is normal for high-spin octahedral nickel(II). © 1969, CSIRO. All rights reserved.