SYNTHESIS, CHARACTERIZATION AND CRYSTAL-STRUCTURE OF [MO(CO)5]4TPTA AND [W(CO)5]4TPTA (TPTA=1,4,8,11-TETRAKIS(METHYLDIPHENYLPHOSPHINO)-1,4,8,11-TETRAAZACYCLOTETRADECANE)

被引：5

作者：

PLANINIC, P ^{[1
]}

MEIDER, H ^{[1
]}

MATKOVICCALOGOVIC, D ^{[1
]}

机构：

[1] UNIV ZAGREB, FAC SCI, GEN & INORGAN CHEM LAB, ZAGREB 41000, CROATIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 483卷 / 1-2期

关键词：

MOLYBDENUM; TUNGSTEN; CARBONYL; CRYSTAL STRUCTURE;

D O I：

10.1016/0022-328X(94)87165-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Pentacarbonyl complexes of molybdenum and tungsten with 1,4,8,11-tetrakis(methyldiphenylphosphino)-1,4,8,11-tetraazacyclotetradecane (TPTA) have been prepared and characterized. The compounds possess four M(CO)5 units per ligand, with an octahedral coordination environment for each metal atom, all bound to the phosphorus donors from the pendant arms.

引用

页码：205 / 212

页数：8

共 24 条

[1]

[Anonymous], 1974, INT TABLES XRAY CRYS, VIV

[2]

Braterman P. S., 1975, METAL CARBONYL SPECT

[3] PREPARATION AND CONDENSATION-REACTIONS OF METAL-COMPLEXES OF R2PNSO (R = ME, PH) WITH POTASSIUM TERT-BUTOXIDE - X-RAY CRYSTAL-STRUCTURE OF (CO)5MO(PH2PNSO) [J].

CHIVERS, T ;

LENSINK, C ;

RICHARDSON, JF .

ORGANOMETALLICS, 1987, 6 (09) :1904-1909

[4] PI ACIDITY OF TRIS(2-CYANOETHYL)PHOSPHINE - X-RAY STRUCTURAL STUDIES OF M(CO)5P(CH2CH2CN)3(M=CR,MO) AND MO(CO)5P(C6H5)3 [J].

COTTON, FA ;

DARENSBOURG, DJ ;

ILSLEY, WH .

INORGANIC CHEMISTRY, 1981, 20 (02) :578-583

[5] LENGTH OF A TUNGSTEN-PHOSPHINE BOND FREE OF EXCESSIVE STERIC INTERACTIONS - CRYSTAL-STRUCTURE OF W(CO)5P(CH3)3 [J].

COTTON, FA ;

DARENSBOURG, DJ ;

KOLTHAMMER, BWS .

INORGANIC CHEMISTRY, 1981, 20 (12) :4440-4442

[6] EXPLORATORY CALCULATIONS OF MEDIUM AND LARGE RINGS .1. CONFORMATIONAL MINIMA OF CYCLOALKANES [J].

DALE, J .

ACTA CHEMICA SCANDINAVICA, 1973, 27 (04) :1115-1129

[7] MOLECULAR GEOMETRY OF SUBSTITUTED BENZENE-DERIVATIVES .2. BOND ANGLE VERSUS ELECTRONEGATIVITY CORRELATION FOR PHENYL DERIVATIVES OF 2ND-ROW ELEMENTS [J].

DOMENICANO, A ;

VACIAGO, A ;

COULSON, CA .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1975, 31 (JUN15) :1630-1641

[8] POLYDENTATE LIGANDS CONTAINING PHOSPHORUS .4. GROUP-6 METAL-CARBONYL DERIVATIVES OF N-(DIPHENYLPHOSPHINO)METHYL DERIVATIVES OF ETHYLENEDIAMINE [J].

GRIM, SO ;

SHAH, DP ;

MATIENZO, LJ .

INORGANIC CHEMISTRY, 1980, 19 (08) :2475-2478

[9]

HARKEMA S, 1979, ACXR PROGRAM ABSORPT

[10] SYNTHESES AND X-RAY CRYSTAL-STRUCTURES OF 2 NEW CLASSES OF MACROCYCLIC LIGANDS HAVING BOTH PHOSPHORUS AND NITROGEN DONOR ATOMS [J].

HOPE, H ;

VIGGIANO, M ;

MOEZZI, B ;

POWER, PP .

INORGANIC CHEMISTRY, 1984, 23 (16) :2550-2552

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