APPLICATION OF INDIUM ATE COMPLEXES TO SYNTHETIC CHEMISTRY - SELECTIVE CONJUGATE ADDITION TO ENONES AND COUPLING WITH ALLYLIC HALIDES

被引：57

作者：

ARAKI, S ^{[1
]}

SHIMIZU, T ^{[1
]}

JIN, SJ ^{[1
]}

BUTSUGAN, Y ^{[1
]}

机构：

[1] NAGOYA INST TECHNOL,DEPT APPL CHEM,GOKISO CHO,SHOWA KU,NAGOYA,AICHI 466,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 12期

关键词：

D O I：

10.1039/c39910000824

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tetraorganoindium ate complexes, prepared by the addition of organolithium reagents to trialkylindium, reacted with alpha,beta-unsaturated ketones in a 1,4-addition fashion; allylic indates derived from allylic indium sesquihalides coupled with allylic halides regio- and stereo-specifically to give high yields of head-to-tail 1,5-dienes.

引用

页码：824 / 825

页数：2

共 17 条

[1] CYCLOPROPANATION OF ELECTRON-DEFICIENT ALKENES AND WIDEQVIST-TYPE SYNTHESIS OF CYCLOPROPANES MEDIATED BY INDIUM METAL [J].

ARAKI, S ;

BUTSUGAN, Y .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (17) :1286-1287

[2] A BARBIER ALLYLATION AND A REFORMATSKY REACTION OF CARBONYL-COMPOUNDS MEDIATED BY INDIUM(I) IODIDE [J].

ARAKI, S ;

ITO, H ;

KATSUMURA, N ;

BUTSUGAN, Y .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 369 (03) :291-296

[3] SYNTHESIS OF BETA-HYDROXYESTERS BY REFORMATSKY REACTION USING INDIUM METAL [J].

ARAKI, S ;

ITO, H ;

BUTSUGAN, Y .

SYNTHETIC COMMUNICATIONS, 1988, 18 (04) :453-458

[4] PREPARATION AND SOME REACTIONS OF ALLYLIC INDIUM REAGENTS [J].

ARAKI, S ;

SHIMIZU, T ;

JOHAR, PS ;

JIN, SJ ;

BUTSUGAN, Y .

JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (07) :2538-2542

[5] INDIUM-INDUCED ALLYLATION OF ACID ANHYDRIDES - A FACILE SYNTHESIS OF ALLYLATED BUTENOLIDES AND PHTHALIDES [J].

ARAKI, S ;

KATSUMURA, N ;

ITO, H ;

BUTSUGAN, Y .

TETRAHEDRON LETTERS, 1989, 30 (12) :1581-1582

[6] INDIUM IN ORGANIC-SYNTHESIS - INDIUM-MEDIATED ALLYLATION OF CARBONYL-COMPOUNDS [J].

ARAKI, S ;

ITO, H ;

BUTSUGAN, Y .

JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (08) :1831-1833

[7] REACTIVITY OF ALLYLIC ORGANOMETALLIC COMPOUNDS OF LITHIUM, SODIUM, MAGNESIUM, ZINC, CADMIUM AND ALUMINUM - RECENT ADVANCES [J].

COURTOIS, G ;

MIGINIAC, L .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1974, 69 (01) :1-44

[8]

HARTLEY FR, 1987, USE ORGANOMETALLIC C

[9] SYNTHESIS OF ALKALINTETRAPHENYLINDATES AND CRYSTAL STRUCTURE OF NA(IN(C6H5)4) [J].

HOFFMANN, K ;

WEISS, E .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1973, 50 (01) :25-31

[10] METAL-ALKYL COMPOUNDS .14. CRYSTAL STRUCTURES OF K(IN(CH3)4), RB(IN(CH3)4) AND CS(IN(CH3)4) [J].

HOFFMANN, K ;

WEISS, E .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1973, 50 (01) :17-24

← 1 2 →