THE SYNTHESIS AND STRUCTURE OF GROUP-5 METAL ALKYL AND ALKYLIDENE COMPLEXES CONTAINING 2,6-DIALKYLPHENOXIDE LIGANDS - X-RAY CRYSTAL-STRUCTURES OF [TA(OC6H3ME2-2,6)2(CH2PH)3], [TA(OC6H3ME2-2,6)4ME], AND [TA(OC6H3BU2T-2,6)2(=CHSIME3)(CH2SIME3)]

被引：66
作者：
CHAMBERLAIN, LR
ROTHWELL, IP
FOLTING, K
HUFFMAN, JC
机构：
[1] PURDUE UNIV,DEPT CHEM,W LAFAYETTE,IN 47907
[2] INDIANA UNIV,CTR MOLEC STRUCT,BLOOMINGTON,IN 47405
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1987年 / 01期
关键词：
D O I：
10.1039/dt9870000155
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
引用
收藏
页码：155 / 162
页数：8
相关论文
共 29 条
[21]   SYNTHETIC AND MECHANISTIC ASPECTS OF INTRAMOLECULAR ALIPHATIC CH BOND ACTIVATION BY TI(IV) AND ZR(IV) METAL CENTERS [J].
LATESKY, SL ;
MCMULLEN, AK ;
ROTHWELL, IP ;
HUFFMAN, JC .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (21) :5981-5987
[22]   CHEMISTRY OF STERICALLY CROWDED ARYLOXIDE LIGANDS .5. SYNTHESIS, STRUCTURE, SPECTROSCOPIC PROPERTIES, AND ELECTROCHEMICAL-BEHAVIOR OF GROUP .4. METAL DERIVATIVES CONTAINING BULKY ARYLOXIDE LIGANDS [J].
LATESKY, SL ;
KEDDINGTON, J ;
MCMULLEN, AK ;
ROTHWELL, IP ;
HUFFMAN, JC .
INORGANIC CHEMISTRY, 1985, 24 (07) :995-1001
[23]   THE CHEMISTRY OF STERICALLY CROWDED ARYL OXIDE LIGANDS .3. CRYSTAL AND MOLECULAR-STRUCTURE AND SPECTROSCOPIC PROPERTIES OF MIXED BENZYL-ARYL OXIDE COMPOUNDS OF ZIRCONIUM [J].
LATESKY, SL ;
MCMULLEN, AK ;
NICCOLAI, GP ;
ROTHWELL, IP ;
HUFFMAN, JC .
ORGANOMETALLICS, 1985, 4 (05) :902-908
[24]   STRUCTURE OF TANTALUM CRESOXIDE [J].
LEWIS, LN ;
GARBAUSKAS, MF .
INORGANIC CHEMISTRY, 1985, 24 (03) :363-366
[25]   PREPARATION OF GROUP-4A COMPLEXES CONTAINING TRI-TERT-BUTYLMETHOXIDE (TRITOX), A STERIC CYCLOPENTADIENYL EQUIVALENT [J].
LUBBEN, TV ;
WOLCZANSKI, PT ;
VANDUYNE, GD .
ORGANOMETALLICS, 1984, 3 (07) :977-983
[26]   CARBON HYDROGEN-BOND ACTIVATION IN EARLY TRANSITION-METAL SYSTEMS [J].
ROTHWELL, IP .
POLYHEDRON, 1985, 4 (02) :177-200
[27]   MULTIPLE METAL-CARBON BONDS .7. PREPARATION AND CHARACTERIZATION OF TA(ETA5-C5H5)2(CH2)(CH3), A STUDY OF ITS DECOMPOSITION, AND SOME SIMPLE REACTIONS [J].
SCHROCK, RR ;
SHARP, PR .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (08) :2389-2399
[28]   PREPARATION AND CHARACTERIZATION OF M(CH3)5 (M=NB OR TA) AND TA(CH2C6H5)5 AND EVIDENCE FOR DECOMPOSITION BY ALPHA-HYDROGEN ATOM ABSTRACTION [J].
SCHROCK, RR .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1976, 122 (02) :209-225
[29]   MULTIPLE METAL-CARBON BONDS .9. PREPARATION AND CHARACTERIZATION OF SEVERAL ALKYLIDENE COMPLEXES, M(ETA-5-C5H5)2(ALKYLIDENE)X (M = TA OR NB), AND X-RAY STRUCTURE OF TA(ETA-5-C5H5)2(CHC6H5)(CH2C6H5) - INVESTIGATION OF ALKYLIDENE LIGAND ROTATION [J].
SCHROCK, RR ;
MESSERLE, LW ;
WOOD, CD ;
GUGGENBERGER, LJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (12) :3793-3800
123