N'-[3-( Hydroxyimino) butan-2-ylidene]4-methylbenzene-1-sulfonohydrazide

被引：3

作者：

Bulhosa, Maria C. S. ^{[1
]}

Gervini, Vanessa Carratu ^{[1
]}

Bresolin, Leandro ^{[1
]}

Locatelli, Aline ^{[2
]}

de Oliveira, Adriano Bof ^{[3
]}

机构：

[1] Univ Fed Rio Grande, Escola Quim & Alimentos, Av Italia Km 08,Campus Carreiros, BR-96201900 Rio Grande, RS, Brazil

[2] Univ Fed Santa Maria, Dept Quim, BR-97105900 Santa Maria, RS, Brazil

[3] Univ Fed Sergipe, Dept Quim, BR-49100000 Sao Cristovao, SE, Brazil

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷

关键词：

data-to-parameter ratio = 18.5; mean σ(C-C) = 0.002 Å; R factor = 0.036; single-crystal X-ray study; T = 293 K; wR factor = 0.112;

D O I：

10.1107/S1600536812003339

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, C 11H 15N 3O 3S, the C - S - N(H) - N linkage is nonplanar, the torsion angle being 75.70 (12)°. The compound has two almost planar fragments linked to the S atom: the hydrazone-derivative fragment [(HONC 4H 6)N - N(H)-] and the tolyl fragment (C 7H 7-) have maximum deviations from the mean plane through the non-H atoms of 0.0260 (10) and 0.0148 (14) Å, respectively. The two planar fragments make an interplanar angle of 79.47 (5)°. In the crystal, molecules are connected through inversion centers via pairs of N - H⋯O and O - H⋯N hydrogen bonds.

引用

页码：O592 / U1336

页数：7

共 6 条

[1] Beger J., 1991, German Patent, Patent No. [DD287027A5., 287027]
[2] Brandenburg K., 2006, DIAMOND
[3] Bruker, 2005, COSMO SAINT SADABS
[4] 4-Methyl-N′-(2-oxoindolin-3-ylidene)benzene-1-sulfonohydrazide
Fonseca, Alexandra de Souza
Storino, Tomas Garcia
Carratu, Vanessa Santana
Locatelli, Aline
de Oliveira, Adriano Bof
[J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O3256 - U1856
[5] A short history of SHELX
Sheldrick, George M.
[J]. ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 : 112 - 122
[6] publCIF: software for editing, validating and formatting crystallographic information files
Westrip, Simon P.
[J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2010, 43 : 920 - 925

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