COBALT(II) COMPLEXES CONTAINING NITROGEN DONOR TRIDENTATE LIGANDS DERIVED FROM 2,6-DIACETYLPYRIDINE AND ANILINE OR 4-METHOXYANILINE

被引：16

作者：

EDWARDS, DA ^{[1
]}

EDWARDS, SD ^{[1
]}

MARTIN, WR ^{[1
]}

PRINGLE, TJ ^{[1
]}

THORNTON, P ^{[1
]}

机构：

[1] UNIV LONDON,QUEEN MARY & WESTFIELD COLL,DEPT CHEM,LONDON E1 4NS,ENGLAND

来源：

POLYHEDRON | 1992年 / 11卷 / 13期

关键词：

D O I：

10.1016/S0277-5387(00)83708-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of cobalt(II) chloride, bromide and isothiocyanate with the tridentate ligands derived from the condensation of 2,6-diacetylpyridine with either aniline or 4-methoxyaniline afford the high-spin five-coordinate complexes of the type [CoX2L] (X = Cl, Br, or NCS; L = tridentate ligand). Reactions of CO(ClO4)2 - 6H2O with an excess of these ligands give mer-octahedral complexes of the type [CoL2][ClO4]2.

引用

页码：1569 / 1573

页数：5

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