RATIONALIZATION OF THE ENTHALPY OF PROTONATION OF POLYAMINES

被引：24

作者：

BARBUCCI, R

BARONE, V

机构：

[1] Istituto Chimico, Naples, 80134

来源：

JOURNAL OF SOLUTION CHEMISTRY | 1979年 / 8卷 / 06期

关键词：

bond formation enthalpy; enthalpy; Protonation of polyamines; solvation enthalpy;

D O I：

10.1007/BF00716002

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The enthalpies of protonation of polyamines in aqueous solution are interpreted in terms of a simple model that does not involve any tautomeric equilibrium. The enthalpies are calculated as the sum of two contributions; bond formation enthalpy (EB) and solvation enthalpy (ES. The results agree well with experimental data. © 1979 Plenum Publishing Corporation.

引用

页码：427 / 438

页数：12

共 36 条

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[8]

BARONE V, UNPUBLISHED

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