COMPATIBLE GLASSY POLYBLENDS BASED UPON POLY(2,6-DIMETHYL-1,4-PHENYLENE OXIDE) - TENSILE MODULUS STUDIES

被引:126
作者
KLEINER, LW
KARASZ, FE
MACKNIGHT, WJ
机构
[1] Department of Polymer Science and Engineering, Materials Research Laboratory, University of Massachusetts, Amherst, Massachusetts
[2] Diamond Shamrock Corporation, T. R. Evans Research Center, Painesville, Ohio, 44077
关键词
D O I
10.1002/pen.760190710
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The mechanical behavior of compatible glassy polyblends based upon poly(2.6‐dimethyl‐ 1,4‐phe nylene oxide) (PPO) was investigated. In particular, the influence of composition, molecular weight, and molecular weight distribution upon the tensile modulus of the blend was assessed. Various possible correlations between the experimentally determined moduli and theory are considered. Included are correlations with density, packing density, composite theory, and lattice fluid theory. The modeling of the properties of mixtures via Simplex lattice design is also presented. Finally, attention is given to the development of compatibility criteria based upon tensile modulus and density measurements. Copyright © 1979 Society of Plastics Engineers, Inc.
引用
收藏
页码:519 / 524
页数:6
相关论文
共 33 条
[1]   LCST BEHAVIOR IN POLYMER BLENDS [J].
BERNSTEIN, RE ;
CRUZ, CA ;
PAUL, DR ;
BARLOW, JW .
MACROMOLECULES, 1977, 10 (03) :681-686
[2]  
BONDI A, 1968, PHYSICAL PROPERTIES
[3]  
Cizek E. P, 1968, U. S. Patent, Patent No. 3383435
[4]   ELASTIC CONSTANTS OF A 2-PHASE COMPOSITE MATERIAL [J].
DAVIES, WEA .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 1971, 4 (08) :1176-&
[5]   THEORY OF ELASTIC COMPOSITE MATERIALS [J].
DAVIES, WEA .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 1971, 4 (09) :1325-&
[6]   EFFECT OF COMPOSITION ON BEHAVIOR OF TRICOMPONENT POLYMER BLENDS - STUDY BY MEANS OF SIMPLEX LATTICE PLANNING OF EXPERIMENT [J].
DIMOV, K ;
DILOVA, E ;
STOYANOV, S .
JOURNAL OF APPLIED POLYMER SCIENCE, 1975, 19 (08) :2087-2098
[7]  
FORGER GR, 1977, MATER ENG, V7, P44
[8]  
FRIED JR, 1976, THESIS U MASSACHUSET
[9]  
GALKIEWICZ R, COMMUNICATION
[10]   SIMPLEX LATTICE DESIGNS FOR MULTICOMPONENT SYSTEMS [J].
GORMAN, JW ;
HINMAN, JE .
TECHNOMETRICS, 1962, 4 (04) :463-&