ULTRAVIOLET PHOTOLYSIS OF HOCL - REMPI MEASUREMENT OF THE RELATIVE POPULATION OF CHLORINE ATOM (P-2) SPIN-ORBIT STATES

被引：12

作者：

BELL, AJ ^{[1
]}

BOGGIS, SA ^{[1
]}

DYKE, JM ^{[1
]}

FREY, JG ^{[1
]}

RICHTER, R ^{[1
]}

SHAW, N ^{[1
]}

TABRIZCHI, M ^{[1
]}

机构：

[1] UNIV SOUTHAMPTON,DEPT CHEM,SOUTHAMPTON SO9 5NH,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1994年 / 90卷 / 01期

关键词：

D O I：

10.1039/ft9949000017

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The nascent chlorine atom (P-2) relative spin-orbit state population resulting from UV photolysis of HOCl has been measured by resonance-enhanced multiphoton ionization (REMPI) in single laser experiments. The ratio of (0.30 +/- 0.07) for Cl*:Cl has been obtained, indicating a stronger preference for production of ground-state Cl(P-2(3/2)) than expected from statistical weights. Also, the Cl+ arrival-time spectra show that most of the energy available in the photolysis is converted into kinetic energy of the photofragments.

引用

页码：17 / 21

页数：5

共 37 条

[21] 266 NM PHOTOLYSIS OF HOCL AND DOCL - LASER-EXCITATION FLUORESCENCE DETECTION OF OH AND OD
HICKMAN, CG
SHAW, N
CRAWFORD, MJ
BELL, AJ
FREY, JG
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1993, 89 (11): : 1623 - 1630
[22] ABINITIO CI STUDY OF STABILITY AND ELECTRONIC-SPECTRUM OF HOCL MOLECULE
HIRSCH, G
BRUNA, PJ
PEYERIMHOFF, SD
BUENKER, RJ
[J]. CHEMICAL PHYSICS LETTERS, 1977, 52 (03) : 442 - 448
[23] THEORETICAL-STUDY OF PHOTO-DISSOCIATION OF HOCL
JAFFE, RL
LANGHOFF, SR
[J]. JOURNAL OF CHEMICAL PHYSICS, 1978, 68 (04) : 1638 - 1648
[24] STUDIES OF REACTIONS OF IMPORTANCE IN THE STRATOSPHERE .3. RATE-CONSTANT AND PRODUCTS OF THE REACTION BETWEEN CLO AND HO2 RADICALS AT 298-K
LECK, TJ
COOK, JEL
BIRKS, JW
[J]. JOURNAL OF CHEMICAL PHYSICS, 1980, 72 (04) : 2364 - 2373
[25] DYNAMICS OF THE REACTIONS OF O((1)D) WITH HCL, DCL, AND CL2
MATSUMI, Y
TONOKURA, K
KAWASAKI, M
TSUJI, K
OBI, K
[J]. JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (10) : 8330 - 8336
[26] MICROWAVE SPECTRUM, STRUCTURE AND ELECTRIC QUADRUPOLE COUPLING CONSTANTS OF HOCL
MIRRI, AM
SCAPPINI, F
CAZZOLI, G
[J]. JOURNAL OF MOLECULAR SPECTROSCOPY, 1971, 38 (02) : 218 - &
[27] ULTRAVIOLET-ABSORPTION SPECTRUM OF GASEOUS HOCL
MISHALANIE, EA
RUTKOWSKI, CJ
HUTTE, RS
BIRKS, JW
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1986, 90 (22) : 5578 - 5584
[28] ULTRAVIOLET-SPECTRUM OF HOCL
MOLINA, LT
MOLINA, MJ
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1978, 82 (22) : 2410 - 2414
[29] PRODUCTION OF OH FROM PHOTOLYSIS OF HOCL AT 307-309 NM
MOLINA, MJ
ISHIWATA, T
MOLINA, LT
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1980, 84 (08) : 821 - 826
[30] THEORETICAL-STUDY OF THE PHOTODISSOCIATION CROSS-SECTIONS AND THE PHOTODISSOCIATION DYNAMICS OF HOCL
NANBU, S
IWATA, S
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (05) : 2103 - 2111

← 1 2 3 4 →