THE CRYSTAL-STRUCTURE OF TETRAETHYLENE GLYCOL COMPLEX OF SODIUM TETRAPHENYLBORATE

被引：3

作者：

UEDA, T ^{[1
]}

NAKAMURA, N ^{[1
]}

机构：

[1] OSAKA UNIV, FAC SCI, DEPT CHEM, TOYONAKA, OSAKA 560, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1992年 / 65卷 / 11期

关键词：

D O I：

10.1246/bcsj.65.3180

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal of 2,2'-[oxybis(ethyleneoxy)]diethanol (tetraethylene glycol or TEG) complex Of sodium tetraphenylborate, [Na(C8H18O5)]B(C6H5)4, is triclinic, P1, with the unit cell dimensions: a=1.1730 (2), b=1.3212 (3), c=1.1408 (2) nm, a=108.83(1), beta=112.40(1), and gamma=67.420(2), Z=2. This compound contains binucear metal complex ion, [Na(C8H18O5)]22+ The sodium ion is coordinated highly asymmetrically by six oxygens in two TEG.

引用

页码：3180 / 3182

页数：3

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