THERMODYNAMICS OF NITRIC-ACID EXTRACTION WITH ISO-BUTANOL .1. WATER ACTIVITY IN ISO-BUTANOL

被引:2
|
作者
SIPKA, VA
RUVARAC, AL
KOPECNI, MM
机构
[1] Boris Kidrič Institute of Nuclear Sciences, 11001, Belgrade
关键词
D O I
10.1080/07366299.1990.11073613
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A numerical procedure was employed to evaluate hydrated water attached to the extractable nitric acid/ iso-butanol complex. The hydratation number was found to be 11, a value favourable in comparison to the hydratation numbers published for straight chain alcohols extractants. Of several tested approaches, the fourth order jnteraction Scatchard equation offers water activity coefficients in the alcohol phase which are in close agreement with the measured ones. © 1990, Taylor & Francis Group, LLC. All rights reserved.
引用
收藏
页码:271 / 282
页数:12
相关论文
共 50 条