SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF [PD-4(MU(3)-CH)(MU-CL)(3)(PBU(3)(T))(4)] - A TETRAHEDRAL PALLADIUM CLUSTER-WITH A MU(3)-METHYLIDYNE LIGAND

被引：18

作者：

BURROWS, AD

MINGOS, DMP

MENZER, S

VILAR, R

WILLIAMS, DJ

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1995年 / 12期

关键词：

D O I：

10.1039/dt9950002107

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The compound [Pd-4(mu(3)-CH)(mu-Cl)(3)(PBu(3)(t))(4)] has been synthesised from [Pd-2(dba)(3)] (dba = dibenzylideneacetone), PBu(3)(t) and CHCl3 and characterised spectroscopically and by single-crystal X-ray analysis; it undergoes substitution reactions with Br- and tertiary phosphines and is a catalyst for the polymerisation of ethyne.

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页码：2107 / 2108

页数：2

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