PACKING OF ATOMS IN LEAD HALOSILICATE GLASSES OF LOW SILICA CONTENT

被引：20
作者：
OSAKA, A
WANG, YH
KOBAYASHI, M
MIURA, Y
TAKAHASHI, K
机构：
[1] Okayama Univ, Japan
来源：
JOURNAL OF NON-CRYSTALLINE SOLIDS | 1988年 / 105卷 / 1-2期
关键词：
Lead Compounds - Silicates - Spectroscopy; Infrared; -; Spectroscopy; Raman;
D O I：
10.1016/0022-3093(88)90338-9
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Infrared and Raman spectra and molar volume were measured for a series of lead halosilicate glasses of composition 30SiO2 &middot(70-x)PbO&middotxPbX2 (02+, free oxide ions coordinated only to Pb, halide ions, and silicate anions are loosely packed in the glass with about 50% packing density.
引用
收藏
页码：63 / 68
页数：6
相关论文
共 24 条
[1]   THE ELECTRICAL-CONDUCTIVITY OF FLUOROZIRCONATE AND CHLORO-FLUOROZIRCONATE GLASSES [J].
ALMEIDA, RM ;
MACKENZIE, JD .
JOURNAL OF MATERIALS SCIENCE, 1982, 17 (09) :2533-2538
[2]  
BINRAN K, 1984, HDB CHEM, V2, P322
[3]  
DONNAY JDH, 1972, CRYSTAL DATA, V2, pC90
[4]   FLUORINE DOPED VITREOUS SILICA ANALYSIS OF FIBER OPTIC PREFORMS BY VIBRATIONAL SPECTROSCOPY [J].
DUMAS, P ;
CORSET, J ;
CARVALHO, W ;
LEVY, Y ;
NEUMAN, Y .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1982, 47 (1-2) :239-241
[5]  
DUPREE R, 1987, PHYS CHEM GLASSES, V28, P78
[6]   STRUCTURE OF LEAD SILICATE-GLASSES DETERMINED BY VIBRATIONAL SPECTROSCOPY [J].
FURUKAWA, T ;
BRAWER, SA ;
WHITE, WB .
JOURNAL OF MATERIALS SCIENCE, 1978, 13 (02) :268-282
[7]  
GALASSO FG, 1970, STRUCTURE PROPERTIES, P90
[8]  
GOETZ J, 1976, J NONCRYST SOLIDS, V22, P391
[9]   STATISTICAL GEOMETRICAL APPROACH TO RANDOM PACKING DENSITY OF EQUAL SPHERES [J].
GOTOH, K ;
FINNEY, JL .
NATURE, 1974, 252 (5480) :202-205
[10]  
KAWAMOTO Y, 1985, MATERIALS SCI FORUM, V5, P767
123