KINETICS OF HYDROGENATION OF SUBSTITUTED NITROBENZENES ON HETEROGENEOUS CATALYSTS IN AQUEOUS SOLUTIONS

被引：0

作者：

Isakina, A. A. ^{[1
]}

Shutov, D. A. ^{[1
]}

Konovalov, A. S. ^{[1
]}

Borisov, A. V. ^{[1
]}

Bobkova, E. S. ^{[1
]}

Rybkin, V. V. ^{[1
]}

机构：

[1] Ivanovo State Univ Chem Technol, Ivanovo, Russia

来源：

IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENII KHIMIYA I KHIMICHESKAYA TEKHNOLOGIYA | 2012年 / 55卷 / 11期

关键词：

nitrobenzene; hydrogenation; 2-propanol; rate; adsorption; acetic acid; sodium hydroxide; skeletal nickel;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The rate of hydrogenation of substituted nitrobenzenes on heterogeneous catalysts in aqueous solutions of 2-propanol was establishesd to depend on the alcohol content. Depending on the mole fraction of 2-propanol, a monotonic change in the solubility of nitro compounds and the shift of K-bands in their EAS is observed. It is significant that the dependence between these characteristics and kinetic parameters of hydrogenetion of substituted nitrobenzens keeps linear one. The transition from water-alcohol media to water solutions of alcohols contening additives of acid or base results in disturbance of these linear relations.

引用

页码：35 / +

页数：6

共 50 条

[1] Hydrogenation of ortho-substituted nitrobenzenes over palladium catalysts
Klyuev, MV
Volkova, TG
Abdullaev, MG
PETROLEUM CHEMISTRY, 2002, 42 (01) : 30 - 33
[2] PLATINUM CATALYSTS FOR HYDROGENATION OF NITROBENZENES
STRUTZ, J
HOPF, E
CHEMIE INGENIEUR TECHNIK, 1988, 60 (04) : 297 - 298
[3] INFLUENCE OF CATALYST MODIFICATION AND SOLVENT ON KINETICS OF REACTIONS OF SUBSTITUTED NITROBENZENES HYDROGENATION
Merkin, A. A.
Korpatenkov, D. O.
Komarov, A. A.
Lefedova, O. V.
IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENII KHIMIYA I KHIMICHESKAYA TEKHNOLOGIYA, 2013, 56 (08): : 82 - +
[4] Transforming Nano Metal Nonselective Particulates into Chemoselective Catalysts for Hydrogenation of Substituted Nitrobenzenes
Serna, Pedro
Corma, Avelino
ACS CATALYSIS, 2015, 5 (12): : 7114 - 7121
[5] Kinetics of sodium maleate hydrogenation over Raney nickel catalysts in aqueous solutions
Lefedova, OV
Trunov, AA
Ulitin, MV
KINETICS AND CATALYSIS, 1998, 39 (02) : 171 - 176
[6] Reduction of substituted nitrobenzenes in aqueous solutions containing natural organic matter
Dunnivant, Frank M.
Schwarzenbach, Rene P.
Macalady, Donald L.
Environmental Science and Technology, 1992, 26 (11):
[7] KINETICS OF HETEROGENEOUS CATALYTIC-HYDROGENATION IN SOLUTIONS
KONYUKHOV, VY
ZYSKIN, AG
KINETICS AND CATALYSIS, 1986, 27 (01) : 199 - 202
[8] Kinetics and models of hydrogenation of phenylhydroxylamine and azobenzene on nickel catalysts in aqueous 2-propanol solutions
Romanenko, Yu. E.
Merkin, A. A.
Komarov, A. A.
Lefedova, O. V.
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2014, 88 (08) : 1323 - 1328
[9] Kinetics and models of hydrogenation of phenylhydroxylamine and azobenzene on nickel catalysts in aqueous 2-propanol solutions
Yu. E. Romanenko
A. A. Merkin
A. A. Komarov
O. V. Lefedova
Russian Journal of Physical Chemistry A, 2014, 88 : 1323 - 1328
[10] KINETICS OF HYDROGENATION AND HYDROFORMYLATION OF PROPYLENE ON HETEROGENEOUS RHODIUM COBALT CATALYSTS
REUT, SI
KAMALOV, GL
GOLODETS, GI
KINETICS AND CATALYSIS, 1991, 32 (03) : 694 - 698

← 1 2 3 4 5 →