共 50 条
POLARIZED RAMAN-STUDY OF MOLECULAR-ORIENTATION IN UNIAXIALLY STRETCHED ATACTIC POLYSTYRENE
被引:22
|作者:
JASSE, B
[1
]
KOENIG, JL
[1
]
机构:
[1] CASE WESTERN RESERVE UNIV,DEPT MACROMOLEC SCI,CLEVELAND,OH 44106
关键词:
CRYSTALS - Orientation - Mathematical techniques - Spectroscopy;
Raman;
D O I:
10.1002/pol.1980.180180406
中图分类号:
O63 [高分子化学(高聚物)];
学科分类号:
070305 ;
080501 ;
081704 ;
摘要:
In the reported experiments, polarized Raman intensities have been obtained from thin films of uniaxially oriented atactic polystyrene. The study was made using the 623 cm** minus **1 radial skeletal eta //6//b vibration of the benzene ring. Values of the fourth-order as well as second-order terms in the expansion of the orientation distribution were obtained for draw ratios between 1. 5 and 7. 7. Values for P//2(cos theta ) agree well with the values obtained from infrared dichroism.
引用
收藏
页码:731 / 738
页数:8
相关论文