REACTION OF 9-NITROANTHRACENE WITH SODIUM CYANIDE IN DIMETHYLFORMAMIDE

被引：22
作者：
LANDOLT, RG
SNYDER, HR
机构：
[1] Department of Chemistry and Chemical Engineering, University of Illinois, Urbana
来源：
JOURNAL OF ORGANIC CHEMISTRY | 1968年 / 33卷 / 01期
关键词：
D O I：
10.1021/jo01265a082
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The interaction of 9-nitroanthracene with sodium cyanide in DMF at room temperature gives a solution which exhibits an electron paramagnetic resonance signal and from which a series of products, including 9-cyano-10-nitroanthracene, 9-amino-10-cyanoanthracene, 9,10-dicyanoanthracene, 9-cyano-10-anthranol, and 9-cyano-10-anthrone can be isolated. Product distributions under a variety of reaction conditions have been studied. Product formation is discussed in terms of oxidation-reduction of a Meisenheimer adduct and nucleophilic substitution. © 1968, American Chemical Society. All rights reserved.
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页码：403 / &
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