ANODIC-OXIDATION OF GLASSY-CARBON SURFACES

被引：19

作者：

LAUSEVIC, Z ^{[1
]}

JENKINS, GM ^{[1
]}

机构：

[1] UNIV COLL SWANSEA,DEPT MAT ENGN,SWANSEA JA2 8PP,WALES

来源：

CARBON | 1986年 / 24卷 / 05期

关键词：

ANODES - Oxidation - ELECTRIC BATTERIES - Electrodes;

D O I：

10.1016/0008-6223(86)90156-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Glassy carbon electrodes have been proposed for electrochemical analysis because of their chemical inertness and good electrical conductivity. Carbon has also been proposed in new designs of lead-acid batteries. If glassy carbon is used as an anode, there is a danger of irreversible alteration of surface morphology and chemistry, resulting eventually in spalling erosion by the formation of a non-adherent oxidized layer leading to catastrophic exfoliation at high voltages/current densities.

引用

页码：651 / 652

页数：2

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